(3-chloroacetylacetonato)(N,N-dimethyl,N'-benzyl-1,2-diaminoethane)copper(II) perchlorate | 1171821-86-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (3-chloroacetylacetonato)(N,N-dimethyl,N'-benzyl-1,2-diaminoethane)copper(II) perchlorate
• 英文别名: Cu(3-chloroacetylacetonate)(N,N-dimethyl,N'-benzyl-1,2-diaminoethane)ClO4
• CAS: 1171821-86-5
• 化学式: C₁₆H₂₄ClCuN₂O₂*ClO₄
• 分子量: 474.828
• InChiKey: ZZCPPODJPVIRPG-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  (3-chloroacetylacetonato)(N,N-dimethyl,N'-benzyl-1,2-diaminoethane)copper(II) perchlorate 、 水 、 四苯硼钠 以 甲醇 、 水 为溶剂， 以80%的产率得到aqua(3-chloroacetylacetonato)(N,N-dimethyl,N'-benzyl-1,2-diaminoethane)copper(II) tetraphenylborate
  参考文献：
  名称：

  Syntheses and characterization of mixed-chelate copper(II) complexes containing different counter ions; spectroscopic studies on solvatochromic properties

  摘要：

  Solvatochromic mixed-chelate copper(II) complexes, [Cu(Cl-acac)(diamine)]X (where Cl-acac = 3-chloroacetylacetonate ion, diamine = N,N'-dimethyl,N'-benzyl-1,2-diaminoethane and X = B(Ph)(4)(-), PF6-, BF4- and ClO4-), have been prepared. The complexes were characterized on the basis of elemental analysis, molar conductance, UV-Vis and IR spectroscopies. Single crystals of [Cu(Cl-acac)(diamine)(H2O)]PF6, complex 2, were also characterized by X-ray diffraction. The influence of the solvent polarity and counter ions on the v(max) values of the d-d bands of the complexes have been investigated by means of visible spectroscopy. All the complexes demonstrated negative solvatochromism. A multi-parametric equation has been utilized to explain the solvent effect on the d-d transition of the complexes using SPSS/PC software. The stepwise multiple linear regression (SMLR) method demonstrated that the donor power of the solvent plays the most important role in the solvatochromism of the compounds. The relative donor power of the anions X was determined by visible spectra in the solvent dichloromethane. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2011.01.011
• 作为产物：
  描述：

  copper(II) perchlorate hexahydrate 、 N'-苯甲基-N,N-二甲基乙二胺 、 3-氯-2,4-戊二酮 在 Na₂CO₃ 作用下， 以 乙醇 、 水 为溶剂， 以40%的产率得到(3-chloroacetylacetonato)(N,N-dimethyl,N'-benzyl-1,2-diaminoethane)copper(II) perchlorate
  参考文献：
  名称：

  Chromotropism of a new mixed-chelate copper(II) complex

  摘要：

  A new mixed-chelate copper(II) complex with the general formula [Cu(Cl-acac)(diamine)]ClO4, where Cl-acac is 3-chloroacetylacetonate ion and diamine is N,N-dimethyl,N'-benzyl-1,2-diaminoethane, was prepared and characterized on the basis of elemental analysis, spectroscopic and conductance measurements. The mixed-chelate complex is soluble in various solvents and presents an interesting combination of solvato- and thermochromism. Its reversible chromotropism behavior is discussed in detail. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2009.02.023