cadmium iodide * 2 triphenyl phosphine | 14126-39-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: cadmium iodide * 2 triphenyl phosphine
• 英文别名: Cd(triphenylphosphane)2I2；Cd(PPh3)2I2；Diiodocadmium;triphenylphosphane
• CAS: 14126-39-7
• 化学式: C₃₆H₃₀CdI₂P₂
• 分子量: 890.801
• InChiKey: KFNXBXBPUAZMQP-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  8.66
• 重原子数：
  41
• 可旋转键数：
  6
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  吡啶 、 cadmium iodide * 2 triphenyl phosphine 、 ((phenyl)Te)2Hg 以 四氢呋喃 为溶剂， 以80%的产率得到
  参考文献：
  名称：

  On the search of size- and shape-controlled metal chalcogenide cluster compounds

  摘要：

  Hg(TePh)(2) (Ph-phenyl) reacts with CdI(2)(PPh(3))(2), PPhMe(2) (Me-methyl), and PPh(3)/Zn(NO(3))(2)center dot 4H(2)O to give the compounds [Hg(4)(TePh)(7)IPy](n) (Py=pyridine) (1), [Hg(8)Te(TePh)(14)(PPhMe(2))(2)]center dot 0.5DMF (DMF=dimethylformamide) (2) and [Hg(11)(TePh)(18)Te(2)Py(3)](n) (3).While 1 and 3 assemble polymeric clusters, 2 can be described as a super tetrahedron with a Te(2-) ion located in the center. The geometric topology of cluster 3, together with some experimental evidences, suggests that its core is attained by the spontaneous fusion of clusters 1 and 2. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2010.05.002
• 作为产物：
  描述：

  cadmium(II) iodide 在 triphenyl phosphine 作用下， 以 乙醇 为溶剂， 生成 cadmium iodide * 2 triphenyl phosphine
  参考文献：
  名称：

  Evans, R. C.; Mann, F. G.; Peiser, H. S., Journal of the Chemical Society

  摘要：

  DOI：

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Cd: SVol., 20.2, page 788 - 792
  作者：

  DOI：——

  日期：——
• Evans, R. C.; Mann, F. G.; Peiser, H. S., Journal of the Chemical Society
  作者：Evans, R. C.、Mann, F. G.、Peiser, H. S.、Purdie, D.

  DOI：——

  日期：——
• On the search of size- and shape-controlled metal chalcogenide cluster compounds
  作者：Ernesto Schulz Lang、Davi Fernando Back、Gelson Manzoni de Oliveira

  DOI：10.1016/j.jorganchem.2010.05.002

  日期：2010.8

  Hg(TePh)(2) (Ph-phenyl) reacts with CdI(2)(PPh(3))(2), PPhMe(2) (Me-methyl), and PPh(3)/Zn(NO(3))(2)center dot 4H(2)O to give the compounds [Hg(4)(TePh)(7)IPy](n) (Py=pyridine) (1), [Hg(8)Te(TePh)(14)(PPhMe(2))(2)]center dot 0.5DMF (DMF=dimethylformamide) (2) and [Hg(11)(TePh)(18)Te(2)Py(3)](n) (3).While 1 and 3 assemble polymeric clusters, 2 can be described as a super tetrahedron with a Te(2-) ion located in the center. The geometric topology of cluster 3, together with some experimental evidences, suggests that its core is attained by the spontaneous fusion of clusters 1 and 2. (C) 2010 Elsevier B.V. All rights reserved.
• Goel, Ram G.; Henry, William P.; Srivastava, Ramesh C., Inorganic Chemistry, 1981, vol. 20, # 6, p. 1727 - 1731
  作者：Goel, Ram G.、Henry, William P.、Srivastava, Ramesh C.

  DOI：——

  日期：——