[Fe(1-[bis(2-pyridylthio)methyl]pyridine-2-thione(-1H))(pyridine-2-thiolate)] | 1262544-80-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 杂芳族化合物
• 英文名称: [Fe(1-[bis(2-pyridylthio)methyl]pyridine-2-thione(-1H))(pyridine-2-thiolate)]
• CAS: 1262544-80-8
• 化学式: C₂₁H₁₆FeN₄S₄
• 分子量: 508.496
• InChiKey: WFWUJDXDGFWMSM-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Fe(1-[bis(2-pyridylthio)methyl]pyridine-2-thione(-1H))(pyridine-2-thiolate)] 、 高氯酸,吡啶 以 乙腈 为溶剂， 生成
  参考文献：
  名称：

  Rearrangement of the Tris(2-pyridylthio)methanido Ligand in an Iron(II) Complex Containing an Fe−C Bond

  摘要：

  Iron(11) tris(2-pyridylthio)methanido (1) containing an Fe-C bond, obtained from the reaction of tris(2-pyridylthio)methane (HL1) and iron(II) triflate, reacts with protic acid to generate iron(II) bis(2-pyridylthio)carbene (la). The carbene complex is converted to an iron(II) complex (2) of the 1-[bis(2-pyridylthio)methyl]pyridine-2-thione ligand (L-3) upon treatment with a base. Complex 2 reversibly transforms to la in the presence of an acid. During the transformation of 1 to 2, a novel rearrangement of L-1 to L-3 takes place. The iron(II) complexes are reactive toward dioxygen to form the corresponding iron(III) complexes.

  DOI：

  10.1021/ic101913p
• 作为产物：
  描述：

  在 Et₃N 作用下， 以 not given 为溶剂， 生成 [Fe(1-[bis(2-pyridylthio)methyl]pyridine-2-thione(-1H))(pyridine-2-thiolate)]
  参考文献：
  名称：

  Rearrangement of the Tris(2-pyridylthio)methanido Ligand in an Iron(II) Complex Containing an Fe−C Bond

  摘要：

  Iron(11) tris(2-pyridylthio)methanido (1) containing an Fe-C bond, obtained from the reaction of tris(2-pyridylthio)methane (HL1) and iron(II) triflate, reacts with protic acid to generate iron(II) bis(2-pyridylthio)carbene (la). The carbene complex is converted to an iron(II) complex (2) of the 1-[bis(2-pyridylthio)methyl]pyridine-2-thione ligand (L-3) upon treatment with a base. Complex 2 reversibly transforms to la in the presence of an acid. During the transformation of 1 to 2, a novel rearrangement of L-1 to L-3 takes place. The iron(II) complexes are reactive toward dioxygen to form the corresponding iron(III) complexes.

  DOI：

  10.1021/ic101913p