5-[2-(3-formyl-4-hydroxy-5-methylphenyl)propan-2-yl]-2-hydroxy-3-methylbenzaldehyde | 879864-71-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 5-[2-(3-formyl-4-hydroxy-5-methylphenyl)propan-2-yl]-2-hydroxy-3-methylbenzaldehyde
• CAS: 879864-71-8
• 化学式: C₁₉H₂₀O₄
• 分子量: 312.365
• InChiKey: FQLFLNBXZPDGBU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.67
• 重原子数：
  23.0
• 可旋转键数：
  4.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.26
• 拓扑面积：
  74.6
• 氢给体数：
  2.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  5-[2-(3-formyl-4-hydroxy-5-methylphenyl)propan-2-yl]-2-hydroxy-3-methylbenzaldehyde 在 sodium tetrahydroborate 作用下， 以 乙醇 、 甲苯 为溶剂， 反应 3.0h， 生成
  参考文献：
  名称：

  Synthesis and Characterization of New Organic Phosphonates Monomers as Flame Retardant Additives for Polymers

  摘要：

  Commercially available polyphenols react with diethylphosphite to give polyphosphonates, which are easily transformed by LDA in good yields to polyorthohydroxy aryl phosphonates. Moreover, some bis-benzyl aminobenzyl phosphonates have been prepared in good yields. These new monomers are of great relevance for the synthesis of thermal resistant polycondensates containing phosphonate moieties.

  DOI：

  10.1080/10426500701290748
• 作为产物：
  描述：

  乌洛托品 、 4,4'-(1-甲基亚乙基)双(2-甲基苯酚) 在 溶剂黄146 、 硫酸 作用下， 以 水 为溶剂， 反应 10.0h， 以45%的产率得到5-[2-(3-formyl-4-hydroxy-5-methylphenyl)propan-2-yl]-2-hydroxy-3-methylbenzaldehyde
  参考文献：
  名称：

  Synthesis and Characterization of New Organic Phosphonates Monomers as Flame Retardant Additives for Polymers

  摘要：

  Commercially available polyphenols react with diethylphosphite to give polyphosphonates, which are easily transformed by LDA in good yields to polyorthohydroxy aryl phosphonates. Moreover, some bis-benzyl aminobenzyl phosphonates have been prepared in good yields. These new monomers are of great relevance for the synthesis of thermal resistant polycondensates containing phosphonate moieties.

  DOI：

  10.1080/10426500701290748