[Pt(SC6H4Cl-4)2(dppm)] | 221619-17-6

• 分子结构分类: 有机化合物 - 苯类化合物
• 英文名称: [Pt(SC6H4Cl-4)2(dppm)]
• CAS: 221619-17-6
• 化学式: C₃₇H₃₀Cl₂P₂PtS₂
• 分子量: 866.711
• InChiKey: LRZFABYCVNTVAF-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  9.7
• 重原子数：
  44.0
• 可旋转键数：
  8.0
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.03
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  dichloro(bis(diphenylphosphino)methane)platinum(II) 、 [Pt(SC6H4Cl-4)2(dppm)] 、 三氟甲磺酸铊 以 乙腈 为溶剂， 以67%的产率得到[Pt2(μ-SC6H4Cl-4)2(dppm)2][CF3SO3]2
  参考文献：
  名称：

  Thiolato-bridged “Linear” trinuclear platinum complexes [Pt3(μ-SR)4(dppm)2]2+

  摘要：

  Thiolato-bridged tri- and dinuclear platinum complexes of the types [Pt-3(mu-SR)(4)(dppm)(2)](2+) (1) and [Pt-2(mu-ER)(2)(dppm)(2)](2+) (2) (E = S or Se; R = alkyl or aryl; dppm = bis(diphenylphosphino)methane) have been prepared using the mononuclear precursors [Pt(ER)(2)(dppm)]. The complexes have been characterized by NMR (H-1, C-13, P-31 , Pt-195), FT-IR and FAB mass spectral data. The structure of [Pt-3(eta-SC6H4CH3-4)(4)(dppm)(2)][CF3SO3](2).6CH(2)Cl(2) (1d), has been established through X-ray crystallography, revealing a zig-zag arrangement of the three coordination spheres around the platinum atoms. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2003.12.024
• 作为产物：
  描述：

  dichloro(bis(diphenylphosphino)methane)platinum(II) 、 Pb(SC6H4Cl-4)2 以 丙酮 为溶剂， 以84%的产率得到[Pt(SC6H4Cl-4)2(dppm)]
  参考文献：
  名称：

  Synthesis and characterisation of mono- and binuclear palladium and platinum complexes with organochalcogenides

  摘要：

  Mononuclear palladium and platinum complexes of the type M(ER)(2)((PP)-P-boolean AND) [M = Pd or Pt; ER = SPh, SC6H4Cl-4, SC6H4Me-4, SC6F5, SePh, TeC6H4OEt-4; (PP)-P-boolean AND = dppm or dppe] have been prepared and their ability to form dinuclear metal species has been demonstrated. All complexes have been characterised by multinuclear magnetic resonance (H-1, C-13, Se-77, Pt-195) spectral data. The effects of phosphine ligands and organochalcogenides are reflected in the Se-77 and Pt-195 NMR shifts. The shielding of Pt-195 NMR chemical shifts has been interpreted in terms of their binding ability to platinum. The structures of two derivatives, namely [Pd(SC6F5)(2)(dppe)] and [Pd(SePh)(2)(dppe)], have been established by X-ray crystallography. The palladium atom in each of the monomeric structures exists in a square planar geometry. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(98)00335-1