(R)-N-(2-hydroxy-3,5-di-tert-butylbenzyl)-{(1S,2S,4S)-1,7,7-trimethylbicyclo[2.2.1]heptane}-2-sulfinamide | 1416721-15-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (R)-N-(2-hydroxy-3,5-di-tert-butylbenzyl)-{(1S,2S,4S)-1,7,7-trimethylbicyclo[2.2.1]heptane}-2-sulfinamide
• CAS: 1416721-15-7
• 化学式: C₂₅H₄₁NO₂S
• 分子量: 419.672
• InChiKey: KIOOIZFKBATMNP-QDKQGLKTSA-N

反应信息

• 作为产物：
  描述：

  (R,S)-N-(E)-(2-hydroxy-3,5-di-tert-butylbenzylid-ene)-{(1S,2S,4S)-1,7,7-trimethylbicyclo-[2.2.1]heptane}-2-sulfinamide 在 lithium aluminium tetrahydride 作用下， 以 四氢呋喃 为溶剂， 以12%的产率得到(S)-N-(2-hydroxy-3,5-di-tert-butylbenzyl)-{(1S,2S,4S)-1,7,7-trimethylbicyclo[2.2.1]heptane}-2-sulfinamide
  参考文献：
  名称：

  Synthesis and reduction of new sulfinimines with isobornane structure

  摘要：

  Synthesis of sulfenimines proceeding from isobornanethiol with yields up to 78% was performed. They were oxidized to diastereomeric isobornylsulfinimines and the latter were reduced to N-substituted isobornylsulfinamides in high yields.

  DOI：

  10.1134/s1070428012110024