cis-{Pt(PPh2CH=C(Bu(t))-N-N=CHPh)2} | 154790-24-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: cis-{Pt(PPh2CH=C(Bu(t))-N-N=CHPh)2}
• CAS: 154790-24-6
• 化学式: C₅₀H₅₂N₄P₂Pt
• 分子量: 966.017
• InChiKey: UGEVSFIZPQLXSB-AQRMOEOISA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.61
• 重原子数：
  57.0
• 可旋转键数：
  8.0
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.16
• 拓扑面积：
  31.2
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为产物：
  描述：

  在 sodium methoxide 作用下， 以 甲醇 为溶剂， 生成 cis-{Pt(PPh2CH=C(Bu(t))-N-N=CHPh)2}
  参考文献：
  名称：

  Complexes of the bidentate ligands PPh₂CH₂C(Bu^t)NNR₂(R = H or Me) and PPh₂CH₂C(Bu^t)N–NCHPh with palladium and platinum. X-Ray crystal structure of cis-[Pt{PPh₂CH₂C(Bu^t)NNH}₂]

  摘要：

  tert-Butyl diphenylphosphinomethyl ketone dimethylhydrazone L1 reacts with [PtCl2(cod)] (cod = cycloocta-1,5-diene) to give the chelate [PtCl2{PPh2CH2C(Bu(t))=NNMe2}] with a six-membered chelate ring; the corresponding palladium complex was also prepared. The phosphino dimethylhydrazone L1 or the phosphino hydrazone L2 also react with [PtMe2(cod)] to give (PtMe2{PPh2CH2C(But)=NNR2}], (R = Me or H); these platinum(II) complexes react with methyl iodide to give the corresponding trimethylplatinum(IV) complexes [PtMe3I{PPh2CH2C(But)=NNR2}]. Treatment of [PtCl2(cod)] with 2 equivalents of L2 gave the dication cis-[Pt{PPh2CH2C(But)=NNH2}2]2+ isolated as the chloride or chloride hexafluorophosphate salts. The dicationic dichloride reacted with 2 moles of sodium ethoxide to give the neutral cis-[Pt{PPhCH2C(But)=NNH}2]. Treatment of [PdCl2(NCPh)2] with L2 gave [Pd{PPh2CH2C(But)=NNH2}2]Cl2, which with sodium ethoxide gave the neutral trans[Pd{PPh2CH2C(But)=NNH}2]. The mixed azine monophosphine PPh2CH2C(But)=N-N=CHPh L3 with [PdCl2(NCPh)2] gave the chelate complex [PdCl2{PPh2CH2C(But)=N-N=CHPh}] and with [PtMe2(cod)] it gave [PtMe2{PPh2CH2C(But)=N-N=CHPh)]. Treatment of [PtCl2(NCMe)2] with 2 equivalents of L3 gave trans-[PtCl2{PPh2CH2C(But)=N-N=CHPh}2] which on heating gave the dicationic dichloride salt cis-[Pt{PPh2CH2C(But)=N-N=CHPh}2]Cl2. Successive treatments of this salt with 1 mole of sodium methoxide gave cis-[{PPh2CH2C(But)=N-N=CHPh}Pt{PPh2CH=C(But)N-N=CHPh}]+ and cis-[Pt{PPh2CH=C(But)N-N=CHPh}2]. Proton, C-13-{H-1}, P-31-{H-1) NMR and infrared data have been obtained. Crystals of cis-[Pt{PPh2CH2C(But)=NNH2}2 are monoclinic, space group P2(1)/c, with a = 1261.5(2), b = 1794.6(3), c = 1792.0(4) pm and Z = 4; final R = 0.0451 for 4088 observed reflections.

  DOI：

  10.1039/dt9940000103