sodium tBuPhBPf3 | 1210318-31-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: sodium tBuPhBPf3
• 英文别名: sodium tris(pentafluorophenyl)(t-butylphenyl)borate
• CAS: 1210318-31-2
• 化学式: C₂₈H₁₃BF₁₅*Na
• 分子量: 668.188
• InChiKey: FKYHFVXGFXJGCX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.45
• 重原子数：
  45.0
• 可旋转键数：
  4.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  sodium tBuPhBPf3 、 四丁基溴化铵 以 水 为溶剂， 反应 1.0h， 以73%的产率得到tetrabutylammonium tris(pentafluorophenyl)(t-butylphenyl)borate
  参考文献：
  名称：

  Weakly Coordinating Amphiphilic Organoborate Block Copolymers

  摘要：

  Selective functionalization of polystyrene with weakly coordinating organoborate functionalities BAr4- (Ar = Ph, C6F5) has been accomplished by a polymer modification strategy The first examples of perfluoroarylborate block copolymers have been prepared; light scattering and TEEM studies confirm the Formation of reverse micelles, in which the weakly coordinating anion sites are covered by a shell of '"inert" polystyrene. The core of the micelles was successfully loaded with a cationic rhodium complex.

  DOI：

  10.1021/ja908996e
• 作为产物：
  描述：

  4-t-butylphenyl dibromoborane 、 Pentafluorphenylkupfer 在 sodium carbonate 作用下， 以 二氯甲烷 、 乙腈 、 水 为溶剂， 以78%的产率得到sodium tBuPhBPf3
  参考文献：
  名称：

  Weakly Coordinating Amphiphilic Organoborate Block Copolymers

  摘要：

  Selective functionalization of polystyrene with weakly coordinating organoborate functionalities BAr4- (Ar = Ph, C6F5) has been accomplished by a polymer modification strategy The first examples of perfluoroarylborate block copolymers have been prepared; light scattering and TEEM studies confirm the Formation of reverse micelles, in which the weakly coordinating anion sites are covered by a shell of '"inert" polystyrene. The core of the micelles was successfully loaded with a cationic rhodium complex.

  DOI：

  10.1021/ja908996e