[Pd(NCC6H4C6H4O(CH2)6OC6H3CHNC6H4OC10H21)(N,N-dihexyl-N'-benzoyl thiourea)] | 1221071-60-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Pd(NCC6H4C6H4O(CH2)6OC6H3CHNC6H4OC10H21)(N,N-dihexyl-N'-benzoyl thiourea)]
• CAS: 1221071-60-8
• 化学式: C₆₂H₈₀N₄O₄PdS
• 分子量: 1083.83
• InChiKey: HZMJVKQVORQDEI-MFSPNSHTSA-M

反应信息

• 作为产物：
  描述：

  N,N-di-n-hexyl-N'-benzoyl thiourea sodium salt 、 以 二氯甲烷 为溶剂， 以44%的产率得到[Pd(NCC6H4C6H4O(CH2)6OC6H3CHNC6H4OC10H21)(N,N-dihexyl-N'-benzoyl thiourea)]
  参考文献：
  名称：

  Synthesis, mesomorphism and luminescence properties of palladium(II) and platinum(II) complexes with dimeric Schiff base liquid crystals

  摘要：

  A series of ortho-metallated Pd and Pt complexes containing dimeric liquid crystals Schiff base as cyclo-metallated ligands and N-benzoyl thiourea derivatives as co-ligands were prepared and investigated for their liquid crystalline properties. Their structures were assigned based on elemental analysis, IR and H-1 NMR spectroscopy while the mesogenic properties were investigated by DSC and polarising optical microscopy. The complexes show either monotropic or enantiotropic transitions with nematic and smectic A phases being displayed, with the mesomorphic behaviour strongly related to the type of N-benzoyl thiourea as well as the metal center used. The structure of a palladium(II) complex has been solved by Xray diffraction.The platinum(II) complexes show photoluminescence properties both in solution and in solid state at room temperature, with the emission band centered around 600 nm. These are the first examples of metallomesogens based on Schiff base cyclometallated ligands that display luminescence properties. (C) 2009 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.11.028