4-吡啶甲基丙烯酸酯 | 4513-39-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 4-吡啶甲基丙烯酸酯
• 英文名称: 4-cyanobenzyl acrylate
• 英文别名: 2-Propenoic acid, (4-cyanophenyl)methyl ester；(4-cyanophenyl)methyl prop-2-enoate
• CAS: 4513-39-7
• 化学式: C₁₁H₉NO₂
• mdl: MFCD22571154
• 分子量: 187.198
• InChiKey: FXTUULXFOKWMKJ-UHFFFAOYSA-N

物化性质

• 沸点：
  310.8±25.0 °C(Predicted)
• 密度：
  1.13±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  50.1
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  3-己炔 、 4-吡啶甲基丙烯酸酯 在 二氢吡啶 、 [Ir{dF(CF₃)ppy}₂(dtbpy)]PF₆ 、 水 、 N,N-二异丙基乙胺 、 1,2-双(二苯基膦)乙烷 、 cobalt(II) chloride 作用下， 以 乙腈 为溶剂， 反应 18.0h， 以80%的产率得到(E)-4-cyanobenzyl 4-ethylhept-4-enoate
  参考文献：
  名称：

  光氧化还原/钴双催化用于可见光介导的烯烃-炔烃偶联反应

  摘要：

  最近，双重光氧化还原过渡金属催化已成为一种在较温和的反应条件下制备具有挑战性的碳-碳键的有力工具。在本文中，我们报道了在不需要金属还原剂的情况下可见光介导的低价钴催化剂的受控生成。它可以在室温下通过ene-yne偶联形成C–C键。这种双重催化的普遍性通过容纳多个官能团的可观分子多样性的创造得到证明。

  DOI：

  10.1021/acs.orglett.9b01201
• 作为产物：
  描述：

  4-(羟甲基)苯甲腈 、 丙烯酸 在 4-二甲氨基吡啶 、 N,N'-二环己基碳二亚胺 作用下， 以 二氯甲烷 为溶剂， 反应 16.5h， 以40%的产率得到4-吡啶甲基丙烯酸酯
  参考文献：
  名称：

  光氧化还原/钴双催化用于可见光介导的烯烃-炔烃偶联反应

  摘要：

  最近，双重光氧化还原过渡金属催化已成为一种在较温和的反应条件下制备具有挑战性的碳-碳键的有力工具。在本文中，我们报道了在不需要金属还原剂的情况下可见光介导的低价钴催化剂的受控生成。它可以在室温下通过ene-yne偶联形成C–C键。这种双重催化的普遍性通过容纳多个官能团的可观分子多样性的创造得到证明。

  DOI：

  10.1021/acs.orglett.9b01201

文献信息

• METAL FILM MATERIAL AND METHOD FOR MANUFACTURING THE SAME
  申请人：Fujifilm Corporation

  公开号：US20130186672A1

  公开（公告）日：2013-07-25

  The present invention provides a method for manufacturing a metal film material, the method including: applying an ink composition by discharging the ink composition onto a substrate via an inkjet method, the ink composition containing at least one first monomer having at least one group selected from the group consisting of a cyano group, an alkyloxy group, an amino group, a pyridine residue, a pyrrolidone residue, an imidazole residue, an alkylsulfanyl group, or a cyclic ether residue, at least one second monomer that has polyfunctionality, and at least one polymerization initiator, a total monomer content in the ink composition being 85% by mass or greater; forming a cured film by carrying out at least one of light exposure or heating of the ink composition that has been applied; applying a plating catalyst or a precursor thereof to the cured film; and a plating processing step of performing plating with respect to the plating catalyst or precursor thereof that has been applied.

  本发明提供了一种制造金属薄膜材料的方法，该方法包括：通过喷墨方法将含有至少一种第一单体的油墨组成物排放到基板上，所述第一单体至少包含以下组中的一种：氰基、烷氧基、氨基、吡啶残基、吡咯烷酮残基、咪唑残基、烷基硫基或环氧基，同时含有至少一种具有多重功能的第二单体和至少一种聚合引发剂，油墨组成物中的总单体含量为85％或更高；通过进行光照或加热已施加的油墨组成物形成固化膜；将电镀催化剂或其前体应用于固化膜上；并对已应用的电镀催化剂或其前体进行电镀处理步骤。
• METAL-FILM-COATED MATERIAL AND PROCESS FOR PRODUCING THE SAME, METALLIC-PATTERN-BEARING MATERIAL AND PROCESS FOR PRODUCING THE SAME, COMPOSITION FOR POLYMER LAYER FORMATION, NITRILE POLYMER AND METHOD OF SYNTHESIZING THE SAME, COMPOSITION CONTAINING NITRILE POLYMER, AND LAYERED PRODUCT
  申请人：FUJIFILM Corporation

  公开号：EP2078607A1

  公开（公告）日：2009-07-15

  A process for producing a metal film-coated material, the process including: (a1) forming, on a substrate, a polymer layer formed from a polymer which has a functional group capable of interacting with a plating catalyst or a precursor thereof, and is directly chemically bonded to the substrate;(a2) providing a plating catalyst or a precursor thereof to the polymer layer; and (a3) performing plating with respect to the plating catalyst or a precursor thereof. The polymer layer satisfies all of the following requirements (1) to (4): (1) the saturated water absorption coefficient of the polymer layer as measured in an environment of temperature of 25°C and relative humidity of 50 % is 0.01 to 10% by mass; (2) the saturated water absorption coefficient of the polymer layer as measured in an environment of temperature of 25°C and relative humidity of 95 % is 0.05 to 20% by mass; (3) the water absorption coefficient of the polymer layer as measured after 1 hour of immersion in boiling water at 100°C is 0.1 to 30% by mass; and (4) the surface contact angle of the polymer layer as measured after dropping 5 µL of distilled water thereonto and leaving to stand for 15 seconds in an environment of temperature of 25°C and relative humidity of 50 % is 50 to 150 degrees.

  一种生产金属薄膜涂层材料的工艺，该工艺包括：(a1) 在基底上形成聚合物层，该聚合物层由具有能与电镀催化剂或其前体相互作用的官能团的聚合物形成，并直接与基底化学键合；(a2) 向聚合物层提供电镀催化剂或其前体；(a3) 对电镀催化剂或其前体进行电镀。聚合物层满足以下所有要求（1）至（4）：(1) 在温度为 25°C、相对湿度为 50%的环境下测得的聚合物层的饱和吸水系数为 0.01 至 10%（按质量计）； (2) 在温度为 25°C、相对湿度为 95%的环境下测得的聚合物层的饱和吸水系数为 0.(3) 在 100°C 沸水中浸泡 1 小时后测得的聚合物层吸水系数为 0.1 至 30%（按质量计）；以及 (4) 在温度为 25°C 和相对湿度为 50%的环境中，滴入 5 微升蒸馏水并静置 15 秒后测得的聚合物层表面接触角为 50 至 150 度。
• Nitrile group-containing polymer and method of synthesizing the same, composition containing nitrile group-containing polymer, and laminate
  申请人：Fujifilm Corporation

  公开号：EP2105451A2

  公开（公告）日：2009-09-30

  A polymer comprising a unit represented by the following Formula (1), and a unit represented by the following Formula (2): wherein in Formula (1) and Formula (2), R1 to R5 each independently represent a hydrogen atom or a substituted or unsubstituted alkyl group; X, Y and Z each independently represent a single bond, a substituted or unsubstituted divalent organic group, an ester group, an amide group or an ether group; and L1 and L2 each independently represent a substituted or unsubstituted divalent organic group.

  一种聚合物，由下式（1）代表的单元和下式（2）代表的单元组成： 其中，在式 (1) 和式 (2) 中，R1 至 R5 各自独立地代表氢原子或取代或未取代的烷基；X、Y 和 Z 各自独立地代表单键、取代或未取代的二价有机基团、酯基、酰胺基或醚基；以及 L1 和 L2 各自独立地代表取代或未取代的二价有机基团。
• Polymerizable composition, light-shielding color filter, black curable composition, light-shielding color filter for solid-state image pickup device and method of producing the same, and solid-state image pickup device
  申请人：FUJIFILM Corporation

  公开号：EP2112182A1

  公开（公告）日：2009-10-28

  A polymerizable composition includes a titanium black dispersion containing titanium black and an alkali-soluble resin having at least one unsaturated double bond, a polymerizable compound, and a photopolymerization initiator. A black curable composition includes titanium black, an alkali-soluble resin having a weight average molecular weight of from 2000 to less than 20,000 or a weight average molecular weight of 20,000 to 100,000, a solvent, a photopolymerization initiator, and a compound having an ethylenic unsaturated double bond. A light-shielding color filter having a colored region is formed using the polymerizable composition or the black curable composition. A solid-state image pickup device has the light-shielding color filter.

  一种可聚合组合物包括含有钛黑和至少有一个不饱和双键的碱溶性树脂的钛黑分散体、一种可聚合化合物和一种光聚合引发剂。一种黑色固化组合物包括钛黑、重量平均分子量为 2000 至小于 20000 或重量平均分子量为 20000 至 100000 的碱溶性树脂、溶剂、光聚合引发剂和具有乙烯不饱和双键的化合物。利用可聚合组合物或黑色固化组合物形成具有彩色区域的遮光彩色滤光片。固态图像拾取装置具有该遮光彩色滤光片。
• CONDUCTIVE-SUBSTANCE-ADSORBING RESIN FILM, PROCESS FOR PRODUCING CONDUCTIVE-SUBSTANCE-ADSORBING RESIN FILM, METAL-LAYER-COATED RESIN FILM MADE FROM THE SAME, AND PROCESS FOR PRODUCING METAL-LAYER-COATED RESIN FILM
  申请人：Fujifilm Corporation

  公开号：EP2133200A1

  公开（公告）日：2009-12-16

  The invention provides a conductive substance-adsorbing resin film on which a conductive layer being excellent in adhesion to the resin film and having less unevenness at the interface with the resin film can easily be formed, a method for producing the same, a metal layer-coated resin film on which a high definition wiring excellent in adhesion to the insulating resin film can easily be formed, which is obtained by using the conductive substance-adsorbing resin film of the invention, and a method for producing a metal layer-coated resin film that is a material capable of easily producing a printed-wiring board having a high definition wiring. The invention also provides a conductive substance-adsorbing resin film including at least two resin layers, wherein at least one of the resin layers is an adsorbing resin layer having a property of adsorbing a conductive substance or a metal. This conductive substance-adsorbing resin film is allowed to adsorb a metal and subjected to plating, whereby a metal layer-coated resin film can be obtained.

  本发明提供了一种导电物质吸附树脂薄膜，在该薄膜上可以很容易地形成导电层，该导电层与树脂薄膜的附着力极佳，并且与树脂薄膜的界面不平整度较低、通过使用本发明的导电物质吸附树脂膜而获得的、可以容易地在其上形成与绝缘树脂膜附着性优良的高清晰配线的金属层涂覆树脂膜，以及作为能够容易地制造具有高清晰配线的印刷线路板的材料的金属层涂覆树脂膜的制造方法。本发明还提供了一种导电物质吸附树脂薄膜，包括至少两个树脂层，其中至少一个树脂层是具有吸附导电物质或金属特性的吸附树脂层。这种导电物质吸附树脂薄膜可以吸附金属并进行电镀，从而获得金属层涂层树脂薄膜。