fac-[Mn(CO)3(H2O)(1,2-bis(diphenylphosphino)ethane)](BF4)*water | 247939-32-8

• 英文名称: fac-[Mn(CO)3(H2O)(1,2-bis(diphenylphosphino)ethane)](BF4)*water
• CAS: 247939-32-8
• 化学式: BF₄*C₂₉H₂₆MnO₄P₂*H₂O
• 分子量: 660.228
• InChiKey: YJCXGNXYOUIQMD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  fac-[Mn(CO)3(H2O)(1,2-bis(diphenylphosphino)ethane)](BF4)*water 、 sodium azide 以 水 为溶剂， 以100%的产率得到fac-Mn(CO)3(azide)(1,2-bis(diphenylphosphino)ethane)
  参考文献：
  名称：

  The preparation and reactions of the azides of fac-Mn(CO)3(P-P)N3. The X-ray crystal structures of fac-[Mn(CO)3(P-P)(OH2)]BF4, fac-Mn(CO)3(P-P)() [(P-P)=dppe and depe], and fac-[Mn(CO)3(depe)(PPh3)]BF4

  摘要：

  A simple three-step, high-yield synthesis of the titled azides from Mn-2(CO)(10) and P-P is described involving the intermediate aqua complexes, fac-[Mn(CO)(3)(P-P)(H2O)]BF4, 3a,b. The aqua ligand is very labile; it is easily exchanged for D2O, PPh3, and NO2-. Crystal structures of the two titled aqua complexes and fac-[Mn(CO)(3)(depe)(PPh3)]BF4, 6a, are reported. The aqua complexes react instantaneously with aqueous NaN3 to give quantitative yields of the corresponding covalent azides which undergo the expected 1,3-dipolar additions with CF3CN to give the corresponding tetrazoles whose crystal structures are also reported. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(99)00161-8
• 作为产物：
  描述：

  四氟硼酸-二乙醚络合物 、 fac-tricarbonyl(1,2-bis(diphenylphosphino)ethane)hydridomanganese(I) 以 氯仿 为溶剂， 以89%的产率得到fac-[Mn(CO)3(H2O)(1,2-bis(diphenylphosphino)ethane)](BF4)*water
  参考文献：
  名称：

  The preparation and reactions of the azides of fac-Mn(CO)3(P-P)N3. The X-ray crystal structures of fac-[Mn(CO)3(P-P)(OH2)]BF4, fac-Mn(CO)3(P-P)() [(P-P)=dppe and depe], and fac-[Mn(CO)3(depe)(PPh3)]BF4

  摘要：

  A simple three-step, high-yield synthesis of the titled azides from Mn-2(CO)(10) and P-P is described involving the intermediate aqua complexes, fac-[Mn(CO)(3)(P-P)(H2O)]BF4, 3a,b. The aqua ligand is very labile; it is easily exchanged for D2O, PPh3, and NO2-. Crystal structures of the two titled aqua complexes and fac-[Mn(CO)(3)(depe)(PPh3)]BF4, 6a, are reported. The aqua complexes react instantaneously with aqueous NaN3 to give quantitative yields of the corresponding covalent azides which undergo the expected 1,3-dipolar additions with CF3CN to give the corresponding tetrazoles whose crystal structures are also reported. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(99)00161-8