sodium 5-nitro-2-acetamidobenzoate | 1339959-10-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: sodium 5-nitro-2-acetamidobenzoate
• CAS: 1339959-10-2
• 化学式: C₉H₇N₂O₅*Na
• 分子量: 246.155
• InChiKey: WTEBRPLWNRTNBF-UHFFFAOYSA-M

反应信息

• 作为反应物：
  描述：

  copper(ll) sulfate pentahydrate 、 sodium 5-nitro-2-acetamidobenzoate 以 not given 为溶剂， 生成 triaquabis(5-nitro-2-acetamidobenzoato)copper(II) dihydrate
  参考文献：
  名称：

  Crystal and molecular structures of triaquabis(5-nitro-2-acetamidobenzoato)copper(II) dihydrate

  摘要：

  A new copper(II) complex [Cu(5-NO(2)-2-CH(3)CONHC(6)H(3)COO)(2)(H(2)O)(3)] center dot 2H(2)O was synthesized by the reaction of sodium 5-nitro-5-acetamidobenzoate with CuSO(4) center dot 5H(2)O (2 : 1), and its structure was determined by X-ray diffraction. Crystals are monoclinic: a = 11.7146(7) angstrom, b = 16.8463(10) angstrom, c = 13.2408(9) angstrom, beta = 113.896(5)degrees, Z = 4, rho(calc) = 1.668 g/cm(3), space group P2(1)/c, R = 0.0338. In the monomer complex, the copper atom has an elongated square-pyramidal coordination (4 + 1); the coordination sphere is formed by two oxygen atoms of the carboxylate groups of two monodentate organic ligands and the three oxygen atoms O(w) of the water molecules (the O(3w) atom is in the axial position). In the structure, the complex molecules are linked by hydrogen bonds involving two uncoordinated water molecules.

  DOI：

  10.1134/s0036023611090166