zinc meso-mono[(3-heptyloxy)phenoxy]tetrabenzoporphyrinate | 1146617-81-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• 英文名称: zinc meso-mono[(3-heptyloxy)phenoxy]tetrabenzoporphyrinate
• CAS: 1146617-81-3
• 化学式: C₄₉H₃₈N₄O₂Zn
• 分子量: 780.256
• InChiKey: KJCWXIPSTIZBLC-YRWPLAAPSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  zinc meso-mono[(3-heptyloxy)phenoxy]tetrabenzoporphyrinate 在 盐酸 、 水 、 氨 作用下， 以 氯仿 、 水 为溶剂， 反应 24.0h， 以76%的产率得到meso-mono[(3-heptyloxy)phenoxy]tetrabenzoporphyrin
  参考文献：
  名称：

  Synthesis and spectral properties of [3-(heptyloxy)phenoxy]acetic acid and its derived meso-sibstituted tetrabenzoporphyrins

  摘要：

  3-Heptyloxyphenol was obtained by reaction of resorcinol with 1-bromoheptane. Further alkylation with monochloroacetc acid resulted in the synthesis of [3-(heptyloxy)phenoxy]acetic acid. Heating of the latter with phthalimide in the presence of zinc acetate afforded zinc complexes of meso-[(3-heptyloxy)phenoxy] tetrabenzoporphyrins whose demetalization gave free porphyrin bases. Spectral properties of the synthesized compounds were studied.

  DOI：

  10.1134/s1070363208090259
• 作为产物：
  描述：

  邻苯二甲酸亚胺 、 [3-(heptyloxy)phenoxy]acetic acid 在 zinc(II) acetate dihydrate 作用下， 反应 0.67h， 以10%的产率得到zinc meso-mono[(3-heptyloxy)phenoxy]tetrabenzoporphyrinate
  参考文献：
  名称：

  Synthesis and spectral properties of [3-(heptyloxy)phenoxy]acetic acid and its derived meso-sibstituted tetrabenzoporphyrins

  摘要：

  3-Heptyloxyphenol was obtained by reaction of resorcinol with 1-bromoheptane. Further alkylation with monochloroacetc acid resulted in the synthesis of [3-(heptyloxy)phenoxy]acetic acid. Heating of the latter with phthalimide in the presence of zinc acetate afforded zinc complexes of meso-[(3-heptyloxy)phenoxy] tetrabenzoporphyrins whose demetalization gave free porphyrin bases. Spectral properties of the synthesized compounds were studied.

  DOI：

  10.1134/s1070363208090259