(N,N-dimethylaminoethylidene)-2,4-di-tert-butyl-6-methyl-phenylarsine | 141888-45-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (N,N-dimethylaminoethylidene)-2,4-di-tert-butyl-6-methyl-phenylarsine
• 英文别名: C-(N,N-dimethylamino)-As-(2,4-di-tert-butyl-6-methylphenyl)ethylidenearsine；1-(2,4-ditert-butyl-6-methylphenyl)arsanylidene-N,N-dimethylethanamine
• CAS: 141888-45-1
• 化学式: C₁₉H₃₂AsN
• 分子量: 349.391
• InChiKey: WZOWNNMVGHDGME-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.63
• 重原子数：
  21
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.63
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  2,4-di-tert-butyl-6-methylphenyl-dichloroarsine 在 lithium aluminium tetrahydride 作用下， 以 四氢呋喃 、 乙醚 、 苯 为溶剂， 反应 5.25h， 生成 (N,N-dimethylaminoethylidene)-2,4-di-tert-butyl-6-methyl-phenylarsine
  参考文献：
  名称：

  Ionkin, A. S.; Nikolaeva, N. V.; Musin, R. Z., Phosphorus, Sulfur and Silicon and the Related Elements, 1992, vol. 66, # 14, p. 257 - 260

  摘要：

  DOI：

文献信息

• Electrochemical reduction of some compounds of two-coordinate phosphorus and arsenic in an aprotic medium
  作者：T. V. Troepol'skaya、G. A. Vagina、�. I. Yakusheva、A. S. Ionkin、N. V. Nikolaeva、B. A. Arbuzov

  DOI：10.1007/bf00864331

  日期：1992.8

  The electrochemical reduction of a series of compounds of two-coordinate phosphorus and arsenic with linear structure was investigated for the first time. The twin polarographic characteristics indicate irreversibility of the electrode process and its complication by kinetic limitations. The products of controlled-potential electrolysis were analyzed, and schemes are presented for the electrochemical reduction, which consists in hydrogenation with cleavage of the P=E bond of most of the studied compounds (1, 2, and 4) and in cleavage of the C(Ar)-P bond in sterically hindered compound 3. The electrolysis products underwent further transformation in the presence of oxygen and moisture of air.