Propyl 2-(2-bromophenyl)acetate | 93579-01-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Propyl 2-(2-bromophenyl)acetate
• CAS: 93579-01-2
• 化学式: C₁₁H₁₃BrO₂
• 分子量: 257.127
• InChiKey: ZUJYDZCAEKPIHD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  14
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-溴溴苄 、 硼酸三丙酯 以46%的产率得到
  参考文献：
  名称：

  WOELL, J. B.;ALPER, H., TETRAHEDRON LETT., 1984, 25, N 35, 3791-3794

  摘要：

  DOI：

文献信息

• Synthesis of esters by rhodium(i) catalyzed borate ester-benzylic bromide carbonylation reactions
  作者：James B. Woell、Howard Alper

  DOI：10.1016/s0040-4039(01)91168-2

  日期：1984.1

  Benzyl halides react with trialkylborates and carbon monoxide, in the presence of 1,5-hexadienerhodium chloride dimer, to give esters In excellent yields. The reaction is applicable to the synthesis of primary, secondary and even tertiary esters.

  在1，5-己二氯化二氯合二聚体的存在下，卤化苄与三烷基硼酸酯和一氧化碳反应，以优异的收率得到酯。该反应适用于伯，仲，甚至叔酯的合成。
• Process for the production of carboxylic acid esters
  申请人：The British Petroleum Company p.l.c.

  公开号：EP0132144A1

  公开（公告）日：1985-01-23

  Carboxylic acid esters are produced by reacting (i) carbon monoxide, (ii) a compound of the formula M(OR)x wherein M is either boron, silicon, aluminium, titanium or zirconium, x is the valency of M and R is a hydrocarbyl group and (iii) a hydrocarbyl halide, wherein the halide moiety is bromide, chloride or iodide, in the presence of a catalyst comprising one or more of the metals rhodium, iridium and cobalt in either elemental or compound form. When M is boron, silicon or aluminium and the halide moiety is chloride, there is preferably added a source of iodide.

  羧酸酯是通过以下反应制得的：(i) 一氧化碳；(ii) 式 M(OR)x 的化合物，其中 M 为硼、硅、铝、钛或锆，x 为 M 的化合价，R 为烃基；(iii) 烃基卤化物，其中卤化物为溴化物、氯化物或碘化物。当 M 为硼、硅或铝且卤化物分子为氯时，最好添加碘源。
• Process for producing copolymer
  申请人：Kawashima Jun

  公开号：US20050014914A1

  公开（公告）日：2005-01-20

  There are provided (I) a process for producing a copolymer of ethylene, an α-olefin having from 3 to 20 carbon atoms and optionally a polyene, which comprises the step of copolymerizing those monomers in a polymerization reactor by feeding the following components (A), (B), (C1) and (D) to the polymerization reactor: (A) a transition metal complex, (B) an organic aluminum compound, (C1) a halogen-containing compound, and (D) a Lewis base, wherein those components are fed to the polymerization reactor without a preliminary contact of (1) the component (A) with the component (B), (2) the component (A) with the component (C1), (3) the component (B) with the component (C1), and (4) the component (B) with the component (D); and (II) a process for producing said copolymer, which comprises the step of copolymerizing those monomers in a polymerization reactor (i) by feeding to the polymerization reactor the components (A), (B), (D), (C2) a halogen-containing compound, which is a derivative of an aryl group-containing carboxylic acid, and (C3) a halogen-containing compound, which is not a derivative of a carboxylic acid, or (ii) by feeding thereto the components (A), (B), (D), (C3), and (C4) a halogen-containing compound, which is a derivative of a carboxylic acid containing an unsaturated bond-carrying linear organic group.

  提供了(I)一种生产乙烯、具有 3 至 20 个碳原子的α-烯烃和任选的一种聚烯的共聚物的工艺，该工艺包括在聚合反应器中通过向聚合反应器加入下列组分(A)、(B)、(C1)和(D)使这些单体共聚的步骤：(A)过渡金属络合物，(B)有机铝化合物，(C1)含卤素化合物，和(D)路易斯碱，其中这些组分在送入聚合反应器时不需要(1)组分(A)与组分(B)，(2)组分(A)与组分(C1)，(3)组分(B)与组分(C1)，和(4)组分(B)与组分(D)的初步接触；和(II) 生产所述共聚物的工艺，该工艺包括在聚合反应器(i)中通过向聚合反应器加入组分(A)、(B)、(D)、(C2)含卤素化合物（含芳基羧酸的衍生物）来共聚这些单体的步骤、和 (C3) 含卤化合物，它不是羧酸的衍生物，或 (ii) 向反应器中加入组分 (A)、(B)、(D)、(C3) 和 (C4) 含卤化合物，它是含有不饱和键载线性有机基团的羧酸的衍生物。
• PROCESS FOR PRODUCING COPOLYMER
  申请人：KAWASHIMA Jun

  公开号：US20070088139A1

  公开（公告）日：2007-04-19

  There are provided (I) a process for producing a copolymer of ethylene, an α-olefin having from 3 to 20 carbon atoms and optionally a polyene, which comprises the step of copolymerizing those monomers in a polymerization reactor by feeding the following components (A), (B), (C1) and (D) to the polymerization reactor: (A) a transition metal complex, (B) an organic aluminum compound, (C1) a halogen-containing compound, and (D) a Lewis base, wherein those components are fed to the polymerization reactor without a preliminary contact of (1) the component (A) with the component (B), (2) the component (A) with the component (C1), (3) the component (B) with the component (C1), and (4) the component (B) with the component (D); and (II) a process for producing said copolymer, which comprises the step of copolymerizing those monomers in a polymerization reactor (i) by feeding to the polymerization reactor the components (A), (B), (D), (C2) a halogen-containing compound, which is a derivative of an aryl group-containing carboxylic acid, and (C3) a halogen-containing compound, which is not a derivative of a carboxylic acid, or (ii) by feeding thereto the components (A), (B), (D), (C3), and (C4) a halogen-containing compound, which is a derivative of a carboxylic acid containing an unsaturated bond-carrying linear organic group.
• US4642370A
  申请人：——

  公开号：US4642370A

  公开（公告）日：1987-02-10