(triethylgermyl)(triphenylgermyl)oxide | 697745-67-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (triethylgermyl)(triphenylgermyl)oxide
• 英文别名: Triethyl(triphenylgermyloxy)germane
• CAS: 697745-67-8
• 化学式: C₂₄H₃₀Ge₂O
• 分子量: 479.682
• InChiKey: CPQXEWCZUKKOMX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.68
• 重原子数：
  27
• 可旋转键数：
  8
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  三苯基氢化锗 以 四氢呋喃 、 乙醚 为溶剂， 生成 (triethylgermyl)(triphenylgermyl)oxide
  参考文献：
  名称：

  Reactivity of 2,6-diethyl-4,8-dimethyl-1,5-dioxo-s-hydrindacene towards radical, anionic and cationic germylation

  摘要：

  The synthesis and diastereoisomeric resolution of 2,6-diethyl-4,8-dimethyl-1,5-dioxo-s-hydrindacene allowed the determination of the structure of the meso compound by X-ray diffractometry. The diastereoisomers were inactive towards radical germylation but reacted with acidic hydrogermanes or germylithium yielding alpha-germylated alcohols. By contrast, they were poorly reactive towards germylamines or SET reactions. This diketone acts as an efficient spin trap in radical hydrogermylation of alkenes. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2003.10.017