methyl (1-butylcarbamoyl)-2-benzimidazolecarbamate | 51510-37-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并咪唑类
• 英文名称: methyl (1-butylcarbamoyl)-2-benzimidazolecarbamate
• 英文别名: methyl-(butylcarbamoyl)-2-benzimidazolecarbamate；methyl N-(1H-benzimidazol-2-yl)-N-(butylcarbamoyl)carbamate
• CAS: 51510-37-3
• 化学式: C₁₄H₁₈N₄O₃
• 分子量: 290.322
• InChiKey: AGZFDMRWOVHNRR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  21
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  87.3
• 氢给体数：
  2
• 氢受体数：
  4

文献信息

• Furfural derivatives as a vehicle
  申请人：RHODIA OPERATIONS

  公开号：US20160000066A1

  公开（公告）日：2016-01-07

  The present invention concerns the use of a furfural derivative of formula (I) in which R represents (i) a —CH═CR′ 1 —COR 1 group, a group a group a group or a —CHO and R′ represents a hydrogen atom or a (C 1 -C 4 )alkyl group, as a chemical vehicle, as a solvent, co-solvent, coalescing agent, crystallization inhibitor, plasticising agent, degreasing agent, etchant, cleaning agent or agent for increasing biological activity, and more particularly as a solvent. It also concerns phytosanitary formulations or resin-solubilising formulations comprising at least one such furfural derivative of formula (I).

  本发明涉及将式(I)中R代表(i) -CH═CR′1-COR1基团，一个基团，一个基团，或-CHO，R′代表氢原子或(C1-C4)烷基基团的糠醛衍生物用作化学载体、溶剂、共溶剂、凝聚剂、结晶抑制剂、增塑剂、脱脂剂、蚀刻剂、清洁剂或增加生物活性的剂，更特别地作为溶剂。还涉及包含至少一种上述式(I)的糠醛衍生物的植物保健配方或树脂溶解配方。
• N'-Phenyl-N-methylurea derivatives, processes for their preparation and their uses as herbicides
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0017706A2

  公开（公告）日：1980-10-29

  Novel N'-phenyl-N-methylurea derivatives of the formula: wherein R is a C4-C10 cycloalkyl group, a C4-C10 cycloalkenyl group, a C4-C10 cycloalkyl group condensed with a benzene ring or substituted with at least one C1-C4 alkyl group or a C4-C,o cycloalkenyl group condensed with a benzene ring or substituted with a C1-C4 alkyl group, Z is a C1-C4 alkylene group which may have an atom of oxygen and/or sulfur at the terminal of and/or inside the carbon chain, Y is an oxygen atom or a sulfur atom, A is a hydrogen atom, a methyl group or a methoxy group and n is an integer of 0 or 1 with the profiso that in the chain consisting of -(Z)n-Y-, oxygen and/or sulfur atoms can not be present in succession, are described, which show pronounced herbicidal activity against a wide variety of weeds in the cultivation of crop plants without any material toxicity to mammals and any chemical injury to said crop plants. The preparation of the compounds and intermediates therefor and the herbicidal activity of the compounds are described and exemplified.

  式中的新型 N'-苯基-N-甲基脲衍生物： 其中 R 是 C4-C10 环烷基、C4-C10 环烯基、与苯环缩合或被至少一个 C1-C4 烷基取代的 C4-C10 环烷基或与苯环缩合或被 C1-C4 烷基取代的 C4-C,o 环烯基，Z 是 C1-C4 亚烷基，该亚烷基可在碳链的末端和/或碳链的内部具有氧原子和/或硫原子，Y 是氧原子或硫原子、A 是氢原子、甲基或甲氧基，n 是 0 或 1 的整数，但在由 -(Z)n-Y- 组成的链中，氧原子和/或硫原子不能连续存在。本文还描述并举例说明了这些化合物及其中间体的制备方法和除草活性。
• Fungicidal compositions for apple canker and powdery mildews
  申请人：Nippon Gohsei Kagaku Kogyo Kabushiki Kaisha

  公开号：EP0010736A1

  公开（公告）日：1980-05-14

  A germicidal composition which contains 2-(2-hydr- oxyethylamino)-3-benzoylpropionates or salts thereof as an active ingredient has excellent control effects for the agricultural and horticultural plants diseases, especially for apple canker and the powdery mildews of various plants. Said composition has little germicidal damage to the plants and extremely weak toxicity to man and beast.

  一种以 2-(2-氢氧乙基氨基)-3-苯甲酰丙酸酯或其盐类为有效成分的杀菌组合物，对农业和园艺植物的病害，特别是苹果腐烂病和各种植物的白粉病有很好的防治效果。 该组合物对植物的杀菌伤害小，对人和动物的毒性极弱。
• Fungicidal haloalkyl polyhaloquinoxaline sulfonates, preparation and use thereof and compositions containing them
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP0020119A1

  公开（公告）日：1980-12-10

  Compounds having the formula wherein X is F, Cl, or Br; R is fluoralkyl of 1-4 carbon atoms and 1-9 fluorine atoms or CCl3; Y is H, F, Cl, Br, CH3, CF3, CCl3, or NO2; and Z is H, F, Cl, Br, CH3, CF3, or CCl3; with the proviso that when R is -CCl3, Y is H, F, Cl or Br and Z is H, may be used for the control of fungal disease of plants, for which purpose they may be formulated into fungicidal compositions in conventional manner. The compounds may be made by reacting a corresponding quinoxaline- sulfonyl chloride with a haloalcohol of the formula RCH2OH.

  具有以下式子的化合物 其中 X 为 F、Cl 或 Br； R 是 1-4 个碳原子和 1-9 个氟原子的氟烷基或 CCl3； Y 是 H、F、Cl、Br、CH3、CF3、 或 NO2；以及 Z 是 H、F、Cl、Br、 、 或 ； 但当 R 为- 时，Y 为 H、F、Cl 或 Br，Z 为 H、 可用于控制植物的真菌疾病，为此可按常规方法将其配制成杀菌组合物。这些化合物可通过相应的喹喔啉磺酰氯与式 RCH2OH 的卤代醇反应制成。
• Fungizide Thioglykolsäureanilide, Verfahren zu ihrer Herstellung und diese enthaltende Schädlingsbekämpfungsmittel
  申请人：HOECHST AKTIENGESELLSCHAFT

  公开号：EP0023332A2

  公开（公告）日：1981-02-04

  Gegenstand der Erfindung sind neue Thioglykolsäureanilide der Formel I, worin R' R = -CHCOR5, Wasserstoff R' = (C1-C4)-Alkyl, Halogen, (C1-C3)-Alkylthio, (C1-C4)-Alkoxy, (C3-C4)-Alkenyl R2 = Wasserstoff, (C1-C4)-Alkyl, Halogen R', R4, R6 = Wasserstoff, Methyl R5 = Hydroxy, (C1-C4)-Alkoxy, (C1-C3)-Alkylthio, (C1-C2)-Alkoxy -(C1-C2)-alkoxy, Amino, (C,-C2)-Alkylamino, Di-(C1-C2)-alkylamino Y = Sauerstoff oder Schwefel R7 = gegebenenfalls substituiertes (C1-C6)-Alkyl, (C3-C6)-Cycloalkyl, (C3-C4)-Alkenyl, (C3-C4;-Alkinyl R8 = Wasserstoff, (C1-C4)-Alkyl R9 = gegebenenfalls substituiertes (C1-C4)-Alkyl, (C3-C4)-Alkenyl, Furfuryl, Tetrahydrofurfuryl, mit der Maßgabe, daß für Y=S nicht beide Reste R8 und R9 (C1-C4)-Alkyl bedeuten R10= -CN, gegebenenfalls substituiertes (C1-C4)-Alkyl, Allyl, Furfuryl, R"= Wasserstoff, gegebenenfalls substituiertes (C1-C4)-Alkyl (C2-C4)-Alkenyl, mit der Maßgabe, daß R" im Falle von R = nicht für (C1-C4)-Alkyl oder halogen-substituiertes (C1-C4)-Alkyl steht, bedeuten, ferner Verfahren zu deren Herstellung sowie deren Verwendung als Schädlingsbekämpfungsmittel.

  本发明涉及式 I 的新型硫代乙醇酸苯胺、 其中 R' R = -CHCOR5、 氢 R' = (C1-C4)-烷基、卤素、(C1-C3)-烷硫基、(C1-C4)-烷氧基、(C3-C4)-烯基 R2 = 氢、(C1-C4)-烷基、卤素 R'、R4、R6 = 氢、甲基 R5 = 羟基、(C1-C4)-烷氧基、(C1-C3)-烷硫基、(C1-C2)-烷氧基-(C1-C2)-烷氧基、氨基、(C,-C2)-烷基氨基、二-(C1-C2)-烷基氨基 Y = 氧或硫 R7 = 任选取代的 (C1-C6)- 烷基、(C3-C6)-环烷基、(C3-C4)-烯基、(C3-C4)-炔基 R8 = 氢、(C1-C4)-烷基 R9 = 任选取代的(C1-C4)-烷基、(C3-C4)-烯基、糠基、四氢糠基，但对于 Y=S 来说，R8 和 R9 都不是(C1-C4)-烷基 R10=-CN、任选取代的（C1-C4）-烷基、烯丙基、糠基、 R"=氢、任选取代的（C1-C4）-烷基（C2-C4）-烯基，但在 R = 的情况下，R "不是（C1-C4）-烷基。 不是（C1-C4）-烷基或卤素取代的（C1-C4）-烷基，以及它们的制备方法和用作杀虫剂的方法。