[Pd(2,4,6-tris(trifluoromethyl)phenyl)I(NMe2(CH2-o-C6H4-I)-N,I)] | 650607-08-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Pd(2,4,6-tris(trifluoromethyl)phenyl)I(NMe2(CH2-o-C6H4-I)-N,I)]
• CAS: 650607-08-2
• 化学式: C₁₈H₁₄F₉I₂NPd
• 分子量: 775.53
• InChiKey: LRDSUDFXMDCREQ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [Pd(dimethylbenzylamine)(2,4,6-tris(trifluoromethyl)phenyl)(OH2)] 、 碘 以 二氯甲烷 为溶剂， 以53%的产率得到[Pd(2,4,6-tris(trifluoromethyl)phenyl)I(NMe2(CH2-o-C6H4-I)-N,I)]
  参考文献：
  名称：

  [Pd(Fmes)I{NMe2(CH2-o-C6H4-I)-N,I}], a palladium(II) complex with I− and organic iodide as trans ligands

  摘要：

  The treatment of [Pd(dmba)(Fmes)(OH2)] with I-2 leads to the formation of [Pd(Fmes)I {NMe2(CH2-o-C6H4-I)-N,I}]. The X-ray structure shows that a new halocarbon ligand, (2-iodobenzyl)dimethylamine has been formed and is acting as N-I chelate. The two different types of iodine, one iodide ligand and one organic iodide coordinated to Pd, are mutually trans and display essentially identical Pd-I distances. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)01435-4