bis(N-methyl(pyridine-2-carboxaldehyde-2'-pyridylhydrazone))nickel(II) | 795236-87-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: bis(N-methyl(pyridine-2-carboxaldehyde-2'-pyridylhydrazone))nickel(II)
• CAS: 795236-87-2
• 化学式: C₂₄H₂₄N₈Ni
• 分子量: 483.198
• InChiKey: ZILJIVAMVZMJEF-ZQSWXEMLSA-N

反应信息

• 作为产物：
  描述：

  bis(pyridine-2-carboxaldehyde-2'-pyridylhydrazonate)nickel(II) 、 碘甲烷 以 乙腈 为溶剂， 生成 bis(N-methyl(pyridine-2-carboxaldehyde-2'-pyridylhydrazone))nickel(II)
  参考文献：
  名称：

  Spectroscopy, electrochemistry, and nucleophilicity of nickel and cobalt complexes of 2′-pyridine carboxaldehyde 2′-pyridyl hydrazone (papyH)

  摘要：

  Nickel and cobalt complexes of pyridine-2-carboxaldehyde-2'-pyridylhydrazone (papyH) and N-methyl(pyridine-2-carboxaldehyde-2'-pyridyl-hydrazone) (papyMe) have been fully characterized through electrochemistry, titration, and alkylation with methyl iodide and compared with existing data on zinc and iron complexes. Both rate constants for alkylation and ligand pKa depend on the coordinated metal and can be understood based on the influence of d electrons on the ligand molecular orbitals. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.08.037