2-[3-[2-[3-[2-[3,5-Bis[2-[3,5-bis(2-trimethylsilylethynyl)phenyl]ethynyl]phenyl]ethynyl]-5-[2-[3,5-bis(2-trimethylsilylethynyl)phenyl]ethynyl]phenyl]ethynyl]-5-(2-trimethylsilylethynyl)phenyl]ethynyl-trimethylsilane | 937395-39-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-[3-[2-[3-[2-[3,5-Bis[2-[3,5-bis(2-trimethylsilylethynyl)phenyl]ethynyl]phenyl]ethynyl]-5-[2-[3,5-bis(2-trimethylsilylethynyl)phenyl]ethynyl]phenyl]ethynyl]-5-(2-trimethylsilylethynyl)phenyl]ethynyl-trimethylsilane
• CAS: 937395-39-6
• 化学式: C₈₆H₉₀Si₈
• 分子量: 1348.34
• InChiKey: VDPHOOAEZIXDNB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  18.52
• 重原子数：
  94
• 可旋转键数：
  26
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.28
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  dicobalt octacarbonyl 、 2-[3-[2-[3-[2-[3,5-Bis[2-[3,5-bis(2-trimethylsilylethynyl)phenyl]ethynyl]phenyl]ethynyl]-5-[2-[3,5-bis(2-trimethylsilylethynyl)phenyl]ethynyl]phenyl]ethynyl]-5-(2-trimethylsilylethynyl)phenyl]ethynyl-trimethylsilane 以 二氯甲烷 为溶剂， 以77.3%的产率得到
  参考文献：
  名称：

  Nanoscale octadecacobalta- and hexacosacobaltaclusters: Synthesis and spectroscopic fingerprinting

  摘要：

  Strategies for the construction of TMS-protected first generation star and dendritic polyynes, which are subsequently metallated to give multiple CO2C2(CO)(6) clusters, are reported. In the absence of crystallographic data, well-resolved C-13 NMR spectroscopy is a powerful technique for confirming the presence of core, inner and peripheral cluster domains. (C) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2006.10.037