(1R,4R)-1,4-dimethyl-7-oxabicyclo[2.2.1]hept-5-ene-2-carbonitrile | 59275-05-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氧唑烯
• 英文名称: (1R,4R)-1,4-dimethyl-7-oxabicyclo[2.2.1]hept-5-ene-2-carbonitrile
• CAS: 59275-05-7；81763-44-2；81763-45-3
• 化学式: C₉H₁₁NO
• 分子量: 149.192
• InChiKey: MIWMPQMHVZOSLJ-SXNZSPLWSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.6
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  33
• 氢给体数：
  0
• 氢受体数：
  2

文献信息

• DIELS-ALDER RING-OPENING PROCESS
  申请人：Nederlandse Organisatie voor toegepast-natuurwetenschappelijk onderzoek TNO

  公开号：US20210115005A1

  公开（公告）日：2021-04-22

  The invention is directed to a process for the ring-opening of a cycloadduct obtainable from a reaction of a furanic compound and a diene, said process comprising contacting the cycloadduct with an acidic mixture comprising sulfuric acid and an activating agent to obtain a ring-opened product. The present invention is particularly directed a continuous process.