nickel(II) (N-(1-pyridin-2-yl-phenylidene)-N'-[2-([2-[(1-pyridin-2-yl phenylidene)amino]ethyl]amino)ethyl]ethane-1,2-diamine) Ni2(N-(1-pyridin-2-ylphenylidene)-N'-[2([2-[(1-pyridin-2-ylphenylidene)amino]ethyl]piperazine-1-yl)ethyl]amine)(thiocyanate)6 | 1318684-04-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: nickel(II) (N-(1-pyridin-2-yl-phenylidene)-N'-[2-([2-[(1-pyridin-2-yl phenylidene)amino]ethyl]amino)ethyl]ethane-1,2-diamine) Ni2(N-(1-pyridin-2-ylphenylidene)-N'-[2([2-[(1-pyridin-2-ylphenylidene)amino]ethyl]piperazine-1-yl)ethyl]amine)(thiocyanate)6
• CAS: 1318684-04-6
• 化学式: C₃₀H₃₂N₆Ni*C₃₈H₃₄N₁₂Ni₂S₆
• 分子量: 1503.86
• InChiKey: OLEASMKDPMLCPY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  N-(1-pyridin-2-ylbenzylidene)-N'-[2-({2-[(1-pyridin-2-ylbenzylidene)amino]ethyl}amino)ethyl]ethane-1,2-diamine 、 硫氰酸铵 、 nickel(II) perchlorate hexahydrate 、 N-((1-pyridin-2-yl)benzylidene)-N'-[2-(4-[2-[((1-pyridin-2-yl)benzylidene)amino]ethyl]piperazin-1-yl)-ethyl]amine 以 甲醇 为溶剂， 以84%的产率得到nickel(II) (N-(1-pyridin-2-yl-phenylidene)-N'-[2-([2-[(1-pyridin-2-yl phenylidene)amino]ethyl]amino)ethyl]ethane-1,2-diamine) Ni2(N-(1-pyridin-2-ylphenylidene)-N'-[2([2-[(1-pyridin-2-ylphenylidene)amino]ethyl]piperazine-1-yl)ethyl]amine)(thiocyanate)6
  参考文献：
  名称：

  An antiferromagnetically coupled dimeric Ni(II) complex anion and its counter cationic monomeric Ni(II) complex, and some other mononuclear transition metal compounds using some neutral ligands

  摘要：

  Synthesis and single crystal X-ray diffraction studies of four transition metal complexes [Mn(L-1)](ClO4)(2) (1), [Cu(L-1)](ClO4)(2) (2), [Ni-2(L-2)(NCS)(6)][Ni(L-1)] (3) and [Mn(bzpy)(NCS)(2)] (4) with neutral ligands [L-1 = N-(1-pyridin-2-yl-phenylidene)-N'-[2-({2-[(1-pyridin-2-yl phenylidene)amino]ethyl}amino)ethyl]ethane-1,2diamine, L-2 = N-(1-pyridin-2-yl-phenylidene)-N'-[2-({2-[(1-pyridin-2-ylphenylidene)amino]ethyl}piperazine-1yl)ethyl]amine, bzpy = 2-benzoylpyridine] are reported. The trinuclear nickel(II) complex 3 is made of a dinuclear anion and a mononuclear cation. Variable-temperature magnetic susceptibility and variable-field magnetisation studies performed on 3 suggest weak antiferromagnetic coupling (J = -0.7 cm(-1)) between the two metals of the dinuclear entity, but no magnetic interaction between the anionic and cationic counterparts. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2011.05.007