zinc(II) 5,15-bis-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-10,20-bis(4-ethyl-phenyl)porphyrin | 1332480-91-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氮杂萘
• 英文名称: zinc(II) 5,15-bis-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-10,20-bis(4-ethyl-phenyl)porphyrin
• CAS: 1332480-91-7
• 化学式: C₄₈H₅₀B₂N₄O₄Zn
• 分子量: 833.961
• InChiKey: WLOQPQUXBIZRPV-IBSAJEPBSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  zinc(II) 5-(4-(bromodibenzothien-6-yl))-(2,8,13,17-tetraethyl-3,7,12,18-tetramethyl)porphyrin 、 zinc(II) 5,15-bis-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-10,20-bis(4-ethyl-phenyl)porphyrin 在 四(三苯基膦)钯 、 caesium carbonate 作用下， 以63%的产率得到zinc(II) 5-{4-[zinc(II)(2,8,13,17-tetraethyl-3,7,12,18-tetramethyl)-porphyrin-5-yl]-dibenzothien-6-yl}-15-(4,4,5,5-tetramethyl-[1,3,2]-dioxaborolan-2-yl)-10,20-bis-(4-ethylphenyl)porphyrin
  参考文献：
  名称：

  Acceleration of the through space S1 energy transfer rates in cofacial bisporphyrin bio-inspired models by virtue of substituents effect on the Förster J integral and its implication in the antenna effect in the photosystems

  摘要：

  在 77 K 时，共面 β-八烷基卟啉/双（介芳基）卟啉二元体的单子 kET 随供体-受体 0-0 荧光峰之间的间隙线性增加。

  DOI：

  10.1039/c1cc12839f
• 作为产物：
  描述：

  、 频那醇硼烷 在 trans-bis(triphenylphosphine)palladium dichloride 、 三乙胺 作用下， 以 1,2-二氯乙烷 为溶剂， 反应 0.5h， 以0.55 g的产率得到zinc(II) 5,15-bis-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-10,20-bis(4-ethyl-phenyl)porphyrin
  参考文献：
  名称：

  Design of Triads for Probing the Direct Through Space Energy Transfers in Closely Spaced Assemblies

  摘要：

  Using a selective stepwise Suzuki cross-coupling reaction, two trimers built on three different chromophores were prepared. These hinters exhibit a D(boolean AND)A(1)-A(2) structure where the donor D (octa-beta-alkyl zinc(II)porphyrin either as diethylhexamethyl, 10a, or tetraethyltetramethyl, 10b, derivatives) through space transfers the S-1 energy to two different acceptors, di(4-ethylbenzene) zinc(II)porphyrin (A(1); acceptor 1) placed cofacial with D, and the corresponding free base (A(2); acceptor 2), which is meso-meso-linked with A(1). This structure design allows for the possibility of comparing two series of assemblies, 9a,b (D(boolean AND)A(1)) with 10a,b (D-boolean AND(A) over cap (1)-A(2)), for the evaluation of the S-1 energy transfer for the global process D*-> A(2) in the timers. From the comparison of the decays of the fluorescence of D, the rates for through space energy transfer, k(ET) for 10a,b (k(ET) approximate to 6.4 X 10(9) (10a), 5.9 X 10(9) s(-1) (10b)), and those for the corresponding cofacial D(boolean AND)A(1) systems, 9a,b, (k(ET) approximate to 5.0 x 10(9) (9a), 4.7 X 10(9) s(-1) (9b)), provide an estimate for k(ET) for the direct through space D*-> A(2) Process (Le., k(ET)(D(boolean AND)A(1)-A(2)) - k(ET)(D(boolean AND)A(1)) = k(ET)(D*-> A(2)) similar to 1 x 10(9) s(-1)). This channel of relaxation represents similar to 15% of k(ET) for D*-> A(1).

  DOI：

  10.1021/ic3026655