diphenyltin bis(dimethylxanthate)(S,S';S,S') | 87059-04-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: diphenyltin bis(dimethylxanthate)(S,S';S,S')
• 英文别名: diphenyltin bis(methyldithiocarbamate)；diphenyltin methylxanthate
• CAS: 87059-04-9
• 化学式: C₁₆H₁₆O₂S₄Sn
• 分子量: 487.276
• InChiKey: OASYCSVELOUHOS-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  sodium methyl xanthate 、 二苯基二氯化锡 以 二氯甲烷 为溶剂， 以83.7%的产率得到diphenyltin bis(dimethylxanthate)(S,S';S,S')
  参考文献：
  名称：

  NEW ORGANOTIN XANTHATES R₂Sn(S₂COR′)₂AND R₃SnS₂COR′ (R = Me, Ph and R = Me, CH₂Ph). MOLECULAR STRUCTURE OF BIS(O-METHYL-DITHIOCARBONATO)-DIPHENYLTIN(IV), Ph₂Sn(S₂COMe)₂

  摘要：

  Five new organotin xanthates with general formula R2Sn(S2COR ')(2) and R3SnS2COR ' (R = Me and Ph and R ' = Me and CH2Ph) were prepared and characterized by elemental analyses, IR and NMR spectra. The crystal and molecular structure of was determined by X-ray diffraction. The compound Ph2Sn(S2COMe)(2), M = 487.22 is triclinic, P1, with unit cell dimensions a = 9.0265(14) Angstrom, b = 9.395(2) Angstrom , c = 11.989(2) Angstrom, alpha = 100.919(17)degrees, beta = 96.55(2)degrees, gamma = 97.576 degrees. The tin atom is coordinated by two asymmetrically chelating xanthate ligands [Sn-S(11) = 2.4975(11)Angstrom, Sn-S(12) = 3.0404(12) Angstrom, Sn-S(21) = 2.4938(11)Angstrom, Sn-S(22) = 3.1266(12) Angstrom] and by two phenyl groups.

  DOI：

  10.1081/sim-100104845