3-{3,5-bis-[2-(3,4-didodecyloxyphenyl)ethoxy]phenoxy}propylamine | 1352994-18-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 3-{3,5-bis-[2-(3,4-didodecyloxyphenyl)ethoxy]phenoxy}propylamine
• 英文别名: 3-[3,5-Bis[2-(3,4-didodecoxyphenyl)ethoxy]phenoxy]propan-1-amine；3-[3,5-bis[2-(3,4-didodecoxyphenyl)ethoxy]phenoxy]propan-1-amine
• CAS: 1352994-18-3
• 化学式: C₇₃H₁₂₅NO₇
• 分子量: 1128.8
• InChiKey: ZZKGJPVFAVRPKU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  27.4
• 重原子数：
  81
• 可旋转键数：
  60
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  90.6
• 氢给体数：
  1
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  间苯三酚 在 potassium carbonate 、 一水合肼 作用下， 以 乙醇 、 N,N-二甲基甲酰胺 为溶剂， 反应 16.0h， 生成 3-{3,5-bis-[2-(3,4-didodecyloxyphenyl)ethoxy]phenoxy}propylamine
  参考文献：
  名称：

  Simple Cubic Packing of Gold Nanoparticles through Rational Design of Their Dendrimeric Corona

  摘要：

  The first simple-cubic liquid crystal was obtained by coating monodisperse Au nanoparticles (NPs) with a thick corona of amino-substituted organic dendrons. This unusual structure was determined by grazing-incidence diffraction and electron density reconstruction and explained by analyzing the radial density profile of the corona. Another novel structure is proposed for the phase preceding the cubic one: a hexagonal superlattice composed of alternating dense and sparse strings of Au NPs.

  DOI：

  10.1021/ja2095816

文献信息

• Simple Cubic Packing of Gold Nanoparticles through Rational Design of Their Dendrimeric Corona
  作者：Kiyoshi Kanie、Masaki Matsubara、Xiangbing Zeng、Feng Liu、Goran Ungar、Hiroshi Nakamura、Atsushi Muramatsu

  DOI：10.1021/ja2095816

  日期：2012.1.18

  The first simple-cubic liquid crystal was obtained by coating monodisperse Au nanoparticles (NPs) with a thick corona of amino-substituted organic dendrons. This unusual structure was determined by grazing-incidence diffraction and electron density reconstruction and explained by analyzing the radial density profile of the corona. Another novel structure is proposed for the phase preceding the cubic one: a hexagonal superlattice composed of alternating dense and sparse strings of Au NPs.