o-hydroxyacetophenone 4-methoxybenzoyl hydrazone | 119290-28-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: o-hydroxyacetophenone 4-methoxybenzoyl hydrazone
• 英文别名: o-hydroxyacetophenone 4-methoxybenzoylhydrazone；N-salicylidene-p-methoxybenzoylhydrazine；N'-[(1E)-1-(2-hydroxyphenyl)ethylidene]-4-methoxybenzohydrazide；N-[(E)-1-(2-hydroxyphenyl)ethylideneamino]-4-methoxybenzamide
• CAS: 119290-28-7
• 化学式: C₁₆H₁₆N₂O₃
• 分子量: 284.315
• InChiKey: RUJRYDHOXTZRHX-GZTJUZNOSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  21
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  70.9
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  o-hydroxyacetophenone 4-methoxybenzoyl hydrazone 在 lead(IV) acetate 作用下， 以88%的产率得到乙酮,1-[2-(4-甲氧基苯甲酰)苯基]-
  参考文献：
  名称：

  Synthesis of multi-branched dipyrromethene dyes with soluble diethynylphenyl links

  摘要：

  Multi-branched dyes were prepared using a convergent step-by-step procedure. The key dibutoxydiethynylphenyl spacing units were first linked to a difluoroboradipyrromethene (yellow fluorophore) dye via the pseudo-meso position and then selectively cross-coupled to a di-(4-phenyliodo)ethynylborodiisoindolomethene (red emitter via the boron). When ethynylpyrene units were connected at the periphery to the boron of the yellow emitter, efficient cascade singlet energy transfer events occurred from the pyrene to the yellow and to the red emitters. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2008.04.039
• 作为产物：
  描述：

  2'-羟基苯乙酮 、 对甲氧基苯甲酰肼 以 丙醇 为溶剂， 以84%的产率得到o-hydroxyacetophenone 4-methoxybenzoyl hydrazone
  参考文献：
  名称：

  Synthesis of multi-branched dipyrromethene dyes with soluble diethynylphenyl links

  摘要：

  Multi-branched dyes were prepared using a convergent step-by-step procedure. The key dibutoxydiethynylphenyl spacing units were first linked to a difluoroboradipyrromethene (yellow fluorophore) dye via the pseudo-meso position and then selectively cross-coupled to a di-(4-phenyliodo)ethynylborodiisoindolomethene (red emitter via the boron). When ethynylpyrene units were connected at the periphery to the boron of the yellow emitter, efficient cascade singlet energy transfer events occurred from the pyrene to the yellow and to the red emitters. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2008.04.039

文献信息

• Organotin(IV) complexes with tridentate ligand-IV organotin(IV) complexes with N-salicylidene- and N-pyridoxylideneacylhydrazines. crystal and molecular structure of monochloro-monomethyl [(N-salicylidene-p-methoxybenzoylhydrazinato) ono(2)]tin(IV) methanol
  作者：L. Labib、T.E. Khalil、M.F. Iskander、L.S. Refaat

  DOI：10.1016/0277-5387(96)00125-8

  日期：1996.8

  dimethyltin(IV) complexes with N-salicylidene- and N-pyridoxylidene acylhydrazines have been prepared and characterized by IR, UV-vis, 1H NMR and mass spectral techniques. The X-ray crystal structure of monochloro-monomethyl [(N-salicylidene-p-methoxybenzoylhydrazinato)ONO(−2) ]tin (IV) methanol has been determined. In this complex the hydrazone dianion acts as a tridentate ligand and the tin(IV) is six-coordinated

  制备了一系列的单和二甲基锡（IV）配合物，分别与N-水杨基-和N-吡啶氧基亚烷基酰肼，并通过IR，UV-vis，1 H NMR和质谱技术进行了表征。一氯一甲基[（N-水杨基-p已经确定了-甲氧基苯甲酰肼基）ONO（-2）锡（IV）甲醇。在该络合物中，的二价阴离子作为三齿配体，锡（IV）在扭曲的八面体几何结构中呈六配位，酚氧，偶氮甲碱氮，a酸氧和甲基碳占据赤道平面，而氯化物和甲醇氧处于在轴向位置。晶胞中的两个分子通过NHO键连接。讨论了单和二甲基锡（IV）配合物在不同溶剂中的结构，以及溶剂对二甲基锡（IV）配合物的1 H NMR光谱的影响。
• SYNERGISTIC FUNGICIDAL COMPOSITIONS INCLUDING HYDRAZONE DERIVATIVES AND COPPER
  申请人：Young David H.

  公开号：US20120010075A1

  公开（公告）日：2012-01-12

  The present invention relates to the use of mixtures containing hydrazone compounds and copper for controlling the growth of fungi.

  本发明涉及使用含有肼化合物和铜的混合物来控制真菌生长。
• Dey, Kamalendu; Bandyopadhyay, Debasish; Poddar, Sailendra N., Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1992, vol. 22, p. 1111 - 1128
  作者：Dey, Kamalendu、Bandyopadhyay, Debasish、Poddar, Sailendra N.、Mukhopadhyay, Gurucharan、Kauffman, Geoerge B.

  DOI：——

  日期：——
• Dey, Kamalendu; Bandyopadhyay, Debasish; Mandal, Kripasindhu, Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 1991, vol. 30, # 10, p. 872 - 876
  作者：Dey, Kamalendu、Bandyopadhyay, Debasish、Mandal, Kripasindhu

  DOI：——

  日期：——
• Dey, Kamalendu; Mandal, Kripasindhu; Bandyopadhyay, Debasish, Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical
  作者：Dey, Kamalendu、Mandal, Kripasindhu、Bandyopadhyay, Debasish

  DOI：——

  日期：——