tri-EDOT-TTB | 1174223-29-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 双噻吩和低聚噻吩
• 英文名称: tri-EDOT-TTB
• 英文别名: 5-[9,14-Bis(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)-3,8,13-trithiatetracyclo[10.3.0.02,6.07,11]pentadeca-1(12),2(6),4,7(11),9,14-hexaen-4-yl]-2,3-dihydrothieno[3,4-b][1,4]dioxine；5-[9,14-bis(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)-3,8,13-trithiatetracyclo[10.3.0.02,6.07,11]pentadeca-1(12),2(6),4,7(11),9,14-hexaen-4-yl]-2,3-dihydrothieno[3,4-b][1,4]dioxine
• CAS: 1174223-29-0
• 化学式: C₃₀H₁₈O₆S₆
• 分子量: 666.865
• InChiKey: GQFNIWRTRBMWBC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.3
• 重原子数：
  42
• 可旋转键数：
  3
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  225
• 氢给体数：
  0
• 氢受体数：
  12

反应信息

• 作为产物：
  描述：

  2,5,8-三溴苯并[1,2-B:3,4-B':5,6-B“]三噻吩 、 三丁基(2,3-二氢噻吩并[3,4-b]-[1,4]二恶英-5-基)锡烷 在 三苯基膦 、 palladium dichloride 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 24.0h， 以69%的产率得到tri-EDOT-TTB
  参考文献：
  名称：

  Synthesis, Polymerization, and Unusual Properties of New Star-Shaped Thiophene Oligomers

  摘要：

  Terthienobenzene (TTB, 6) was prepared through a new, high yield route along with pi-extended derivatives 10 and 11. Electropolymerization of tris-EDOT derivative 11 results in a highly stable cross-linked conjugated polymer that shows polaron confinement between the TTB units as confirmed by UV-vis-NIR spectroelectrochemistry and EPR.

  DOI：

  10.1021/ol901127q

文献信息

• Synthesis, Polymerization, and Unusual Properties of New Star-Shaped Thiophene Oligomers
  作者：Tyler Taerum、Olena Lukoyanova、Ryan G. Wylie、Dmitrii F. Perepichka

  DOI：10.1021/ol901127q

  日期：2009.8.6

  Terthienobenzene (TTB, 6) was prepared through a new, high yield route along with pi-extended derivatives 10 and 11. Electropolymerization of tris-EDOT derivative 11 results in a highly stable cross-linked conjugated polymer that shows polaron confinement between the TTB units as confirmed by UV-vis-NIR spectroelectrochemistry and EPR.