(η(5)-C5H5)Co(Br)(S2C2(COOMe)2)(CH2SiMe3) | 247103-48-6

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: (η(5)-C5H5)Co(Br)(S2C2(COOMe)2)(CH2SiMe3)
• 英文别名: bromocobalt(2+);cyclopenta-1,3-diene;(Z)-1,4-dimethoxy-1,4-dioxo-3-(trimethylsilylmethylsulfanyl)but-2-ene-2-thiolate
• CAS: 247103-48-6
• 化学式: C₁₅H₂₂BrCoO₄S₂Si
• 分子量: 497.452
• InChiKey: NTSJLXCOAFXYAR-IRYVOTIRSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (η(5)-C5H5)Co(S2C2(COOMe)2)(CHSiMe3) 、 氢溴酸 以 二氯甲烷 为溶剂， 生成 (η(5)-C5H5)Co(Br)(S2C2(COOMe)2)(CH2SiMe3)
  参考文献：
  名称：

  Electrochemical Methods:  Analyses of Structures and Determination of Properties of the Cobaltadithiolene Derivatives [CpCoX(S₂C₂(COOMe)₂)(CHR¹R²)] (X = Cl, Br, and I)

  摘要：

  The electrochemical behavior of cobaltadithiolene derivatives [CpCoX(S2C2(COOMe)(2))((CHRR2)-R-1)] (X = Cl, Br, and I, (R-1, R-2) = (H, H), (H, COOEt), (COOMe, COOMe), and (H, SiMe3)) showed the easy elimination of halide, and the formation of an equilibrium system between these complexes and their corresponding cation complexes and eliminated halide. We report a methodology that proves the existence of this equilibrium in solutions together with their redox behavior according to the application and uses of electrochemical measurements.

  DOI：

  10.1021/om990181h