[Co(HNDC)2(H2O)2] | 263152-35-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [Co(HNDC)2(H2O)2]
• CAS: 263152-35-8
• 化学式: C₁₄H₁₆CoN₆O₄S₄
• 分子量: 519.576
• InChiKey: ZSVCJPCKGFKARA-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  水 、 potassium 3-nicotinoyldithiocarbazate 、 cobalt(II) chloride 以 水 为溶剂， 以70%的产率得到[Co(HNDC)2(H2O)2]
  参考文献：
  名称：

  Transition Metal Chelates Derived from Potassium Nicotinoyldithiocarbazate (KHNDC)

  摘要：

  Mononuclear and polynuclear chelates of nicotinoyldithiocarbazate (HNDC-) with Fe(III), Mn(II), Fe(II), Co(II), Ni(II), Zn(II), Cd(II), Hg(II), Pd(II), Cu(I) and Ag(I) have been prepared. The chelates have been characterized by chemical and thermal (TG, DTG, DTA) analyses, molar conductivity, spectral (UV-Visible, IR, NMR) and magnetic susceptibility measurements. The molar conductivities of the complexes lie in the non-electrolyte range whilst KHNDC is a 1:1 electrolyte. The IR spectral data show that KHNDC behaves in a monoanionic bidentate or tetradentate and dianionic tetradentate manner. The ligand field parameters (B, Dq, beta) for the Fe(III), Co(II) and Ni(II) complexes were calculated and related to the electronic environments. The solid metal acetate complexes have a unique decomposition exotherm profile which can be used as a rapid and sensitive tool for the detection of acetate-containing complexes.

  DOI：

  10.1080/00945710009351758