bismuth trichloride (pyridine-2-aldehyde thiosemicarbazone) | 142002-20-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: bismuth trichloride (pyridine-2-aldehyde thiosemicarbazone)
• CAS: 142002-20-8
• 化学式: C₇H₈BiCl₃N₄S
• 分子量: 495.573
• InChiKey: FRHZBRZCRNWNOC-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (吡啶-2-基亚甲基氨基)硫脲 、 氯化铋 以 甲醇 为溶剂， 生成 bismuth trichloride (pyridine-2-aldehyde thiosemicarbazone)
  参考文献：
  名称：

  Synthesis and structural studies of complexes of Sb(III) and Bi(III) with thiosemicarbazones

  摘要：

  Several new complexes of Sb(III) and Bi(III) with thiosemicarbazones of furfuraldehyde, thiophene-2-carbaldehyde, indol-3-carbaldehyde and pyridine-2-carbaldehyde have been prepared and characterized by elemental analysis, conductivity, molecular weight determination and IR, H-1- and C-13-NMR spectral studies. The ligands form complexes of the type MX3L[M = Sb(III) or Bi(II1); X = chloride; L = ligand] which are found to be non-electrolytes in DMF. Spectral data indicate that the thiosemicarbazones act as bidentate ligands through the azomethine nitrogen and sulphur.

  DOI：

  10.1007/bf00810942