(2,3,7,8,12,13,17,18-octaethyl-5-{4-[15-(4-iodophenyl)-5,10,10,15,20,20-hexamethylporphyrinogen-5-yl]phenylethynyl}porphyrinato)copper(II) | 1254039-96-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (2,3,7,8,12,13,17,18-octaethyl-5-{4-[15-(4-iodophenyl)-5,10,10,15,20,20-hexamethylporphyrinogen-5-yl]phenylethynyl}porphyrinato)copper(II)
• CAS: 1254039-96-7
• 化学式: C₇₆H₈₁CuIN₈
• 分子量: 1296.98
• InChiKey: MQHNNVAYIKSAQH-PVJKGAEUSA-N

反应信息

• 作为反应物：
  描述：

  5-ethynyl-octaethylporphyrin 、 (2,3,7,8,12,13,17,18-octaethyl-5-{4-[15-(4-iodophenyl)-5,10,10,15,20,20-hexamethylporphyrinogen-5-yl]phenylethynyl}porphyrinato)copper(II) 在 bis-triphenylphosphine-palladium(II) chloride 、 copper(l) iodide 、 三乙胺 作用下， 以 甲苯 为溶剂， 反应 24.0h， 以25%的产率得到10,20-bis[4-(2,3,7,8,12,13,17,18-octaethylporphyrin-5-ylethynyl)phenyl]-5,5,10,15,15,20-hexamethylporphyrinogen copper(II) complex
  参考文献：
  名称：

  Synthesis of cyclophane-like porphyrin-calix[4]pyrrole conjugates

  摘要：

  New cyclophane-like porphyrin-calix[4] pyrrole conjugates were synthesized on the basis of meso-ethynyloctaethylporphyrin, and their physicochemical properties were studied.

  DOI：

  10.1134/s107042801008021x
• 作为产物：
  描述：

  10-(4-iodophenyl)-20-[4-(2,3,7,8,12,13,17,18-octaethylporphyrin-5-ylethynyl)phenyl]-5,5,10,15,15,20-hexamethylporphyrinogen 在 copper diacetate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以91%的产率得到(2,3,7,8,12,13,17,18-octaethyl-5-{4-[15-(4-iodophenyl)-5,10,10,15,20,20-hexamethylporphyrinogen-5-yl]phenylethynyl}porphyrinato)copper(II)
  参考文献：
  名称：

  Synthesis of cyclophane-like porphyrin-calix[4]pyrrole conjugates

  摘要：

  New cyclophane-like porphyrin-calix[4] pyrrole conjugates were synthesized on the basis of meso-ethynyloctaethylporphyrin, and their physicochemical properties were studied.

  DOI：

  10.1134/s107042801008021x