[(hydridotris(pyrazolyl)borate)Ru(trimethylphosphine)2(NH3)][phenylacetylide] | 389570-18-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [(hydridotris(pyrazolyl)borate)Ru(trimethylphosphine)2(NH3)][phenylacetylide]
• 英文别名: azane;ethynylbenzene;ruthenium(2+);trimethylphosphane;tri(pyrazol-1-yl)boranuide
• CAS: 389570-18-7
• 化学式: C₈H₅*C₁₅H₃₁BN₇P₂Ru
• 分子量: 584.414
• InChiKey: WFRYMUPFTSFNTJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.44
• 重原子数：
  34
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.26
• 拓扑面积：
  54.5
• 氢给体数：
  1
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  [(hydridotris(pyrazolyl)borate)Ru(II)(PMe3)2(NH2)] 、 苯乙炔 以 氘代四氢呋喃 为溶剂， 生成 [(hydridotris(pyrazolyl)borate)Ru(trimethylphosphine)2(NH3)][phenylacetylide]
  参考文献：
  名称：

  Conner, David; Jayaprakash; Wells, Michael B., Inorganic Chemistry, 2003, vol. 42, # 15, p. 4759 - 4772

  摘要：

  DOI：

文献信息

• Synthesis and Reactivity of the Octahedral d⁶ Parent Amido Complexes TpRu(L)(L‘)(NH₂) (Tp = Hydridotris(pyrazolyl)borate; L = L‘ = PMe₃, P(OMe)₃; L = CO, L‘ = PPh₃) and [TpRu(PPh₃)(NH₂)₂][Li]
  作者：K. N. Jayaprakash、David Conner、T. Brent Gunnoe

  DOI：10.1021/om010739x

  日期：2001.12.1

  A series of octahedral ruthenium (II) parent amido complexes of the type TpRu(L)(L')(NH2) (L/L' = neutral and two-electron-donor ligands) and [TpRu-(PPh3)(NH2)(2)][Li] (Tp = hydridotris(pyrazolyl)borate) have been prepared. Preliminary reactivity studies indicate that the amido moieties are highly basic: for example, TpRu(L)(L')(NH2) complexes deprtonate phenylacetylene at room temperature to form [TpRu(L)(L')(NH3)][PhC2] ion pairs, as determined by H-1 NMR spectroscopy.