tetraphenylantimony 2,5-dimethylbenzenesulfonate | 209463-46-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: tetraphenylantimony 2,5-dimethylbenzenesulfonate
• 英文别名: (tetraphenyl-λ5-stibanyl) 2,5-dimethylbenzenesulfonate
• CAS: 209463-46-7；368445-47-0
• 化学式: C₃₂H₂₉O₃SSb
• 分子量: 615.396
• InChiKey: KIOARGLFJGHEPZ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  4.54
• 重原子数：
  37
• 可旋转键数：
  7
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  51.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  triphenylbismuth bis(2,5-dimethylbenzenesulfonate) 以 丙酮 、 甲苯 为溶剂， 生成 tetraphenylantimony 2,5-dimethylbenzenesulfonate
  参考文献：
  名称：

  Synthesis, structure and reactions of μ-oxobis(arenesulfonatotriarylbismuth)

  摘要：

  醋酮中三芳基铋双（芳磺酸盐）的水解反应生成了通式为[Ar3Bi(OSO2Ar’)]2O（其中Ar=Ph，p-Tol；Ar’=Ph，C6H4Me-4，C6H3Me2-2,4，C6H3Me2-3,4）的铋衍生物。通过X射线衍射确定了μ-氧双[（3,4-二甲基苯磺酸根）三苯基铋]的结构。该分子具有中心对称线性结构，桥连氧原子位于反转中心。铋原子具有扭曲的三角双锥配位，桥连氧原子和芳磺酸根位于轴向位置。Bi-C和Bi-O的键长分别为2.200(2)、2.204(3)和2.442(2) Å，Bi-Obr的键长为2.067(1) Å。

  DOI：

  10.1007/s11176-005-0011-x

文献信息

• ——
  作者：V. V. Sharutin、O. K. Sharutina、I. I. Pavlushkina、I. V. Egorova、A. P. Pakusina、D. B. Krivolapov、A. T. Gubaidullin、I. A. Litvinov

  DOI：10.1023/a:1012385524010

  日期：——

  Tetraphenylantimony arenesulfonates and diphenylbismuth arenesulfonates were prepared by reaction of triphenylbismuth bis(arenesulfonates) with triphenylstibine in toluene at 25 degreesC. The crystal and molecular structure of diphenylbismuth 2,4-dimethylbenzenesulfonate was studied by single crystal X-ray diffraction. The molecules of the compound in the crystal form chains of Ph2BiOSO2C6H3Me2-2,4 fragments linked with oxygen atoms of the sulfo group of the bridging arenesulfonate ligand.
• ——
  作者：V. V. Sharutin

  DOI：10.1023/a:1023463212564

  日期：——

  Pentaarylantimony Ar3Sb (Ar = Ph, p-Tol) arylates diarylbismuth arylsulfonates Ar2BiOSO2Ar' (Ar' = C6H4Me-4; C6H3Me2-2,4, C6H3Me2-2,5) in ether at 20 degreesC (48 h) to form triarylbismuth in yields of up to 95%. The second reaction product is tetraarylantimony arenesulfonate. The reaction of pentaphenylantimony with phenylbismuth bis(arenesulfonate) PhBi(OSO2Ar')(2) under the same conditions leads to formation of diphenylbismuth arenesulfonate and tetraphenylantimony arenesulfonate in yields of up to 90%.
• Sharutin; Sharutina; Zhitkevich, Russian Journal of General Chemistry, 2000, vol. 70, # 6, p. 859 - 866
  作者：Sharutin、Sharutina、Zhitkevich、Kharsika、Bliznyuk、Pakusina、Bel'skii

  DOI：——

  日期：——