C_2h, anti-4b,8b,11b,15b,19b,22b,22d,22e-octamethyl-4b,8b,11b,15b,19b,22b,22d,22e-octahydrobisbenzo[5,6]indeno[1',2',3':3,4]pentaleno[1,2-b:1',2'-i]anthracene | 1354700-35-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: C_2h, anti-4b,8b,11b,15b,19b,22b,22d,22e-octamethyl-4b,8b,11b,15b,19b,22b,22d,22e-octahydrobisbenzo[5,6]indeno[1',2',3':3,4]pentaleno[1,2-b:1',2'-i]anthracene
• 英文别名: anti-bis-tribenzotriquinacene
• CAS: 1354700-35-8
• 化学式: C₅₄H₄₆
• 分子量: 694.959
• InChiKey: WHTSTEUMYQJHPD-PMECYBOVSA-N

反应信息

• 作为产物：
  描述：

  C_s, anti-10,21-epoxy-4b,8b,11b,15b,19b,22b,22d,22e-octamethyl-4b,8b,10,11b,15b,19b,21,22b,22d,22e-decahydrobisbenzo[5,6]indeno[1',2',3':3,4]pentaleno[1,2-b:1',2'-i]anthracene 在 lithium aluminium tetrahydride 、 四氯化钛 、 三乙胺 作用下， 以 四氢呋喃 为溶剂， 反应 0.5h， 以55%的产率得到C_2h, anti-4b,8b,11b,15b,19b,22b,22d,22e-octamethyl-4b,8b,11b,15b,19b,22b,22d,22e-octahydrobisbenzo[5,6]indeno[1',2',3':3,4]pentaleno[1,2-b:1',2'-i]anthracene
  参考文献：
  名称：

  Single-wing Extended Tribenzotriquinacenes via Bowl-shaped Dehydrobenzene and Isobenzofuran Tribenzotriquinacene Derivatives

  摘要：

  Monoaryne and monoisobenzofuran analogues of a C-3v-symmetrical tribenzotriquinacene (TBTQ) were generated in situ and trapped with various dienes and dienophiles, respectively. In this way, a series of single-wing extended TBTQ derivatives bearing the bowl-shaped TBTQ unit in different topographical expositions have become accessible. This includes some novel tribenzotriquinacene "dimers", in which two TBTQ bowls are attached in syn- or anti-orientation at the terminal positions of rigid linker units. Several of these compounds have been characterized by both spectroscopy and X-ray structural analysis. The efficient access to the TBTQ "dimers" studies of novel container compounds and supramolecular architectures.

  DOI：

  10.1021/jo2022668