[Hg(TePh)(diethyldithiophosphate)]n | 1422188-86-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Hg(TePh)(diethyldithiophosphate)]n
• 英文别名: [Hg(TePh){S2P(OEt)2}]n
• CAS: 1422188-86-0
• 化学式: C₄H₁₀O₂PS₂*C₆H₅Te*Hg
• 分子量: 590.524
• InChiKey: SJCVBLNZXUYOIV-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  2.31
• 重原子数：
  17.0
• 可旋转键数：
  4.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  18.46
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为产物：
  描述：

  mercury(II) O,O-diethyl dithiophosphate 、 ((phenyl)Te)2Hg 以 N,N-二甲基甲酰胺 为溶剂， 反应 1.0h， 以85%的产率得到[Hg(TePh)(diethyldithiophosphate)]n
  参考文献：
  名称：

  On the synthesis and structural analysis of some coordination polymers derived from Hg(TeAr)2 involving dithio ligands

  摘要：

  Hg(TePh)(2) (Ph = phenyl) reacts with Hg(dedtc)(2) (dedtc = diethyldithiocarbamate), as well as with Hg(dedtp)(2) (dedtp = diethyldithiophosphate) and sodium pyrrolidine dithiocarbamate to give the coordination polymers [Hg(Teph)(S2CNEt2)](n) (1), [Hg(TePh)(S2P(OEt)(2))](n) (2), and [Hg(TePh)(S2CNC4H8)](n) (3); Hg{Te(dmb)}(2) (dmb = 2,6-dimethoxybenzene) and Hg{Te(mes)}(2) (mes = 2,4,6-trimethylbenzene) react with NaS2CNC4H8 to yield the polymers [Hg(Te(dmb)(S2CNC4H8))](n) (4) and [Hg(Te(mes)(S2CNC4H8)}](n) (5), as well as the mononuclear complexes [Hg(dmb)(S2CNC4H8)] (6) and [Hg(mes)(S2CNC4H8)] (7)The compounds 1, 2 and 3 present a helical structure along the Hg-Te bonds, while 4 and 5 show a zigzag arrangement. In 3, 4 and 5 each Hg atom is linked to two sulfur atoms of one dithio ligand. Compounds 6 and 7 are mononuclear, and probably also decomposition products of 4 and 5, respectively. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.11.017