(2R,3R)-2-((1S,2R)-2-acetoxy-1,3-bis(benzyloxy)propyl)-1-acetyl-1,2,3,6-tetrahydropyridin-3-yl acetate | 1236041-31-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (2R,3R)-2-((1S,2R)-2-acetoxy-1,3-bis(benzyloxy)propyl)-1-acetyl-1,2,3,6-tetrahydropyridin-3-yl acetate
• CAS: 1236041-31-8
• 化学式: C₂₈H₃₃NO₇
• 分子量: 495.573
• InChiKey: MPTISSHDKNICKV-HPQIJTKRSA-N

反应信息

• 作为反应物：
  描述：

  (2R,3R)-2-((1S,2R)-2-acetoxy-1,3-bis(benzyloxy)propyl)-1-acetyl-1,2,3,6-tetrahydropyridin-3-yl acetate 在 四氧化锇 作用下， 以 水 、 丙酮 、 叔丁醇 为溶剂， 反应 14.0h， 生成
  参考文献：
  名称：

  Synthesis of 1,4-dideoxy-1,4-iminoheptitol and 1,5-dideoxy-1,5-iminooctitols from d-xylose

  摘要：

  The synthesis of iminosugars from inexpensive D-xylose in high yields has been developed. The key step in this synthesis involves Wittig olefination or chelation-controlled attack of Grignard reagents on lactol and ring-closing metathesis using first or second generation Grubbs' catalysts. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.carres.2010.04.016
• 作为产物：
  描述：

  (2R,3R,4S,5R)-4-(N-allylacetamido)-1,3-bis(benzyloxy)hept-6-ene-2,5-diyl diacetate 在 RuCl2(1,3-dimesityl-imidazolidin-2-yl)(PCy3)(=CHPh) 作用下， 以 二氯甲烷 为溶剂， 反应 14.0h， 以88%的产率得到(2R,3R)-2-((1S,2R)-2-acetoxy-1,3-bis(benzyloxy)propyl)-1-acetyl-1,2,3,6-tetrahydropyridin-3-yl acetate
  参考文献：
  名称：

  Synthesis of 1,4-dideoxy-1,4-iminoheptitol and 1,5-dideoxy-1,5-iminooctitols from d-xylose

  摘要：

  The synthesis of iminosugars from inexpensive D-xylose in high yields has been developed. The key step in this synthesis involves Wittig olefination or chelation-controlled attack of Grignard reagents on lactol and ring-closing metathesis using first or second generation Grubbs' catalysts. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.carres.2010.04.016