trans-dichloro(ethylenediamine-N,N'-di-3-propanoato)platinum(IV)*H2O | 462653-78-7

• 英文名称: trans-dichloro(ethylenediamine-N,N'-di-3-propanoato)platinum(IV)*H2O
• CAS: 462653-78-7
• 化学式: C₈H₁₄Cl₂N₂O₄Pt*H₂O
• 分子量: 486.211
• InChiKey: WYDJJJYKARVZEB-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  potassium hexachloropalatinate(IV) 、 O,O-diethyl-ethylenediamine-N,N'-di-3-propanoate dihydrochloride 、 水 在 lithium hydroxide 作用下， 以 水 为溶剂， 以64.58%的产率得到trans-dichloro(ethylenediamine-N,N'-di-3-propanoato)platinum(IV)*H2O
  参考文献：
  名称：

  Complex compounds of platinum(IV) and O,O-dialkyl-ethylenediamine-N,N′-di-3-propanoate ligands. A structural evidence for geometry of hydrolytic product of some esters

  摘要：

  Depending on the ester alkyl group, the reaction of O,O-dialkylethylenediamine-N,N'-di-3-propanoate ligands (R(2)eddp) with potassium hexachloroplatinate(IV) afforded trans-dichloro(ethylenediamine-N,N'-di-3-propanoato)platinum(IV) and tetrachloro(O,O-dialkyl-ethylenediamine-N,N'-di-3-propanoato)platinum(IV) complexes. The complexes were characterized by elemental analysis, electronic absorption, infrared, H-1 and C-13 NMR spectroscopy. The trans configuration of [Pt(eddp)Cl-2] complex was confirmed by X-ray crystallography. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2003.11.007