nickel(2+);4,5,9,10,14,15,19,20-octakis(octylsulfanyl)-2,7,12,17,21,23-hexaza-22,24-diazanidapentacyclo[16.2.1.13,6.18,11.113,16]tetracosa-1,3,5,7,9,11(23),12,14,16,18(21),19-undecaene | 133347-52-1

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: nickel(2+);4,5,9,10,14,15,19,20-octakis(octylsulfanyl)-2,7,12,17,21,23-hexaza-22,24-diazanidapentacyclo[16.2.1.13,6.18,11.113,16]tetracosa-1,3,5,7,9,11(23),12,14,16,18(21),19-undecaene
• CAS: 133347-52-1
• 化学式: C₈₀H₁₃₆N₈S₈*Ni
• 分子量: 1525.23
• InChiKey: DPTBBOPWZKUHLC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2,3,7,8,12,13,17,18-octakis(octylsulfanyl)-5,10,15,20-21H,23H-porphyrazine 生成 nickel(2+);4,5,9,10,14,15,19,20-octakis(octylsulfanyl)-2,7,12,17,21,23-hexaza-22,24-diazanidapentacyclo[16.2.1.13,6.18,11.113,16]tetracosa-1,3,5,7,9,11(23),12,14,16,18(21),19-undecaene
  参考文献：
  名称：

  DOPPELT, PASCAL;HUILLE, SYLVAIN, NEW J. CHEM., 14,(1990) N-9, C. 607-609

  摘要：

  DOI：

文献信息

• Columnar Discotic Mesophases from Novel Non-symmetrically Substituted (Octylsulfanyl) Porphyrazines
  作者：Sandra Belviso、Mario Amati、Margherita De Bonis、Francesco Lelj

  DOI：10.1080/15421400701834088

  日期：2008.2.6

  Synthesis and mesomorphism of novel non-symmmetric mono beta-aryl (octylsulfanyl)porphyrazines and their Ni(II) complexes were reported. A recently disclosed asymmetrization procedure led to mono beta-bromo substituted porphyrazines, which provided access to aryl substituted derivatives through Suzuki cross-coupling. UV-Vis spectroscopy showed a bathochromic shift for bromine and aryl substituted nickel complexes. Optical Microscopy and DSC showed that Br derivatives 3a-3b and H-heptakis Ni(II) complex 2b display two columnar mesophases (Col(h) and Col,) stable even at RT and a wide Delta T (100 degrees C). Introduction of the aryl substituent on the macrocycle caused the appearance of only the Col(h) mesophase and lower Delta T.
• Doppelt, Pascal; Huille, Sylvain, New Journal of Chemistry, 1990, vol. 14, p. 607 - 610
  作者：Doppelt, Pascal、Huille, Sylvain

  DOI：——

  日期：——