4-[[2,4,4,6,6-Pentakis[4-[2-[(2-methylpropan-2-yl)oxycarbonylamino]ethyl]phenoxy]-3-aza-1,5-diazanida-4lambda5-phospha-2,6-diphosphoniacyclohex-3-en-2-yl]oxy]benzoic acid | 1071839-74-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-[[2,4,4,6,6-Pentakis[4-[2-[(2-methylpropan-2-yl)oxycarbonylamino]ethyl]phenoxy]-3-aza-1,5-diazanida-4lambda5-phospha-2,6-diphosphoniacyclohex-3-en-2-yl]oxy]benzoic acid
• 英文别名: 4-[[2,4,4,6,6-pentakis[4-[2-[(2-methylpropan-2-yl)oxycarbonylamino]ethyl]phenoxy]-3-aza-1,5-diazanida-4λ5-phospha-2,6-diphosphoniacyclohex-3-en-2-yl]oxy]benzoic acid
• CAS: 1071839-74-1
• 化学式: C₇₂H₉₅N₈O₁₈P₃
• 分子量: 1453.51
• InChiKey: BCNXOPSCNFIUAL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.8
• 重原子数：
  101
• 可旋转键数：
  38
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.42
• 拓扑面积：
  299
• 氢给体数：
  6
• 氢受体数：
  21

反应信息

• 作为反应物：
  描述：

  4-[[2,4,4,6,6-Pentakis[4-[2-[(2-methylpropan-2-yl)oxycarbonylamino]ethyl]phenoxy]-3-aza-1,5-diazanida-4lambda5-phospha-2,6-diphosphoniacyclohex-3-en-2-yl]oxy]benzoic acid 、 O-(benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium tetrafluoroborate 在 N,N-二异丙基乙胺 作用下， 以 二氯甲烷 、 N,N-二甲基甲酰胺 为溶剂， 生成
  参考文献：
  名称：

  Cationic and Fluorescent “Janus” Dendrimers

  摘要：

  Two synthetic routes to "Janus"-type dendrimers possessing ammonium groups on one side and fluorescent dansyl derivatives on the other side are described. These surface-block dendrimers are obtained by the coupling of two different dendrons, built from the hexafunctional cyclotriphosphazene core. Their characterization and their photophysical behavior are reported. The largest compound possesses 10 ammonium groups and 5 dansyl groups; it is potentially useful as a fluorescent label in materials science and biology.

  DOI：

  10.1021/ol801698k