2,3,4,5,6,7,8,9-octahydro-1,9-diphenyl-1H-5,1,9-benzazadiphosphacyclo undecine | 125398-40-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,3,4,5,6,7,8,9-octahydro-1,9-diphenyl-1H-5,1,9-benzazadiphosphacyclo undecine
• 英文别名: (2S,10R)-2,10-diphenyl-6-aza-2,10-diphosphabicyclo[9.4.0]pentadeca-1(15),11,13-triene
• CAS: 125398-40-5
• 化学式: C₂₄H₂₇NP₂
• 分子量: 391.433
• InChiKey: XBUCMPXLAJSLQF-MKPDMIMOSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  27
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  12
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  [nickel(II)dichloride(dimethoxyethane)] 、 2,3,4,5,6,7,8,9-octahydro-1,9-diphenyl-1H-5,1,9-benzazadiphosphacyclo undecine 以 四氢呋喃 为溶剂， 以98%的产率得到dichloro[meso-cis-2,10-diphenyl-6-aza-κN-2,10-diphospha-κ2P-bicyclo[9.4.0]pentadeca-11(1),12,14-triene]nickel(II)
  参考文献：
  名称：

  Kyba, Evan P.; Davis, Raymond E.; Liu, Shiuh-Tzung, Inorganic Chemistry, 1985, vol. 24, # 26, p. 4629 - 4634

  摘要：

  DOI：

文献信息

• Structure of (meso-cis-2,10-diphenyl-6-aza-kN-2,10-diphosphak2Pbicyclo[9.4.0]pentadeca-11(1),12,14-triene)- (bicyclo[2.2.1]heptadiene)rhodium(I) hexafluorophosphate
  作者：Shiuh-Tzung Liu、Ming-Chu Cheng、Shie-Ming Peng

  DOI：10.1016/0022-328x(89)85324-0

  日期：1989.6

  The structure of the title compound has been determined. All three donor atoms in the macrocycle are coordinated to the metal center to form a novel penta-coordinated rhodium(I) species. The N—Rh distance is 2.317(4) Å, slightly longer than normal ones.

  已经确定了标题化合物的结构。大环中的所有三个供体原子均与金属中心配位，形成新颖的五配位铑（I）物种。N-Rh距离为2.317（4）Å，比正常距离稍长。
• Coordination chemistry and catalytic activity of ruthenium(II) complexes containing a phospha-macrocyclic ligand
  作者：Chun-Chin Lee、Hsiao-Ching Huang、Shiuh-Tzung Liu、Yi-Hung Liu、Shie-Ming Peng、Jwu-Ting Chen

  DOI：10.1016/j.poly.2012.06.079

  日期：2013.3

  Substitution of [RuCl2(CO)(3)(THF)], [RuCl2(dmso)(4)] and [RuCl2(PPh3)(3)] with a macrocyclic ligand, 2,3,4,5,6, 7,8,9-octahydro-1,9-diphenyl-1H-5,1,9-benzazadiphosphacyclo undecine (11-P2NH), provided [Ru(11-P2NH)Cl-2(CO)] (3), [Ru(11-P2NH)Cl-2(dmso)] (4) and [Ru(11-P2NH)Cl-2(CH3CN)] (5), respectively. These complexes were characterized by elemental analyses as well as NMR spectroscopy. The structure of 3 was further confirmed by X-ray diffraction analysis. The octahedral geometry around the ruthenium center is in agreement with the Werner's "coordination" bonding concepts. The chelate rings of the macrocycle toward Ru(II) center adopting into chair conformations were revealed. Furthermore, these ruthenium complexes were found to be active for N-alkylation of dibenzylamine with alcohols. (C) 2012 Elsevier Ltd. All rights reserved.
• Coordination of an amino-phosphino macrocycle with(η5-cyclopentadienyl)-and(η5-pentamethylcyclopentadienyl)-iron complexes
  作者：Chung-Yuan Liu、Ming-Chu Cheng、Shie-Ming Peng、Shiuh-Tzung Liu

  DOI：10.1016/0022-328x(94)80050-2

  日期：1994.4

  The coordination chemistry of a phospha-macrocycle meso-cis-2,10-diphenyl-6-aza-2,10-diphenylphabicyclo[9.4.0]pentadeca-11(1),12,14-triene (11-P2NH) with (eta5-cyclopentadienyl)dicarbonyliodoiron and (eta5-pentamethylcyclopentadienyl)dicarbonyliodoiron was investigated. Thus 11-P2NH reacts with CpFe(CO)2I in benzene under photochemical conditions to yield a mixture of [P,P',N-(11-P2NH)FeCp]I (2) and [P,P'-(11-P2NH)Fe(CO)Cp]I (3). Conversion of 3 into 2 was achieved by photochemical treatment of 3 in acetonitrile. The amine donor of the macrocycle in 2 was slowly transformed into a coordinating imine moiety. Similar behaviour was observed for the pentamethylcyclopentadienyl analogue. The crystal structure of [P,P',N-(11-P2NH)FeCp*]I is determined.