| 1346170-36-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 1346170-36-2
• 化学式: C₄₄H₅₆MgN₄
• 分子量: 665.26
• InChiKey: YRKSNRWCFZZBOI-BMURMYISSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  N,N'-二均三甲苯基-2,3-丁烷二亚胺 在 氢化钾 、 magnesium chloride 作用下， 以 四氢呋喃 为溶剂， 反应 72.0h， 以0.5 g的产率得到
  参考文献：
  名称：

  Syntheses and Structures of Magnesium Complexes with Reduced α-Diimine Ligands

  摘要：

  The reduction of neutral alpha-diimine ligands bearing different substituents on the N-aryl rings by different amounts of potassium metal and subsequent reaction with anhydrous MgCl2 in THF afforded a series of magnesium compounds, [(L-iPr)Mg2--(THF)(2)]center dot THF (2), [(L-Mes)Mg2-(THF)(3)] (3), [(L-iPr)(2)Mg-]center dot THF (4), [(L-Mes)(2)Mg-] (5), and [(L-Mes)(2)Mg2-(eta(6):eta(6)-K(THF)(2))][K(THF)(6)]center dot(THF)(2) (6) (L-iPr = [(2,6-(Pr2C6H3)-Pr-i)NC-(Me)](2)), L-Mes = [(2,4,6-Me3C6H2)NC(Me)](2)). Complexes 2-6 have been characterized by single-crystal X-ray diffraction, elemental analysis, NMR spectroscopy, and EPR studies (for 4 and 5). The noninnocent alpha-diimine ligands exist as the dianionic form in compounds 2, 3, and 6 and as a monoanion in 4 and 5. Effects of the ligand substituents and the amount of the reducing agent on the structure of the product have been discussed.

  DOI：

  10.1021/om2003199