bis[2-(3-nitrophenylnitrilomethylidyne)phenolato-N,O]zinc(II) | 226217-93-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis[2-(3-nitrophenylnitrilomethylidyne)phenolato-N,O]zinc(II)
• CAS: 226217-93-2
• 化学式: C₂₆H₁₈N₄O₆Zn
• 分子量: 547.842
• InChiKey: KLTLCRHVYOURAO-ZNVPEIAMSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  6-{[(3-硝基苯基)氨基]亚甲基}-2,4-环己二烯-1-酮 、 zinc(II) acetate dihydrate 以 甲醇 为溶剂， 生成 bis[2-(3-nitrophenylnitrilomethylidyne)phenolato-N,O]zinc(II)
  参考文献：
  名称：

  Zinc(II) complexes of bidentate Schiff base ligands containing methoxyphenyl and nitrophenyl groups

  摘要：

  In the title compounds, bis[2-(3-nitrophenylnitrilomethylidyne)phenolato-N,O]zinc(II), [Zn(C13H9N2O3)(2)], and bis[2-(3-methoxyphenylnitrilomethylidyne)phenolato-N,O]zinc(II), [Zn(C14H12NO2)(2)], the tricilinic unit cell contains two inversion-related molecules, In both compounds, the Zn atom is in a slightly distorted tetrahedral coordination involving O and N atoms of two bidentate ligands, The dihedral angle defined by the two chelate rings is 98.09(4)degrees for the methoxyphenyl complex and 98.05(7)degrees for the nitrophenyl complex. The molecules are crosslinked via intermolecular hydrogen bonds.

  DOI：

  10.1107/s0108270198015406