[4-[[1-[2-[[4-(Hydroxymethyl)phenyl]methoxy]naphthalen-1-yl]naphthalen-2-yl]oxymethyl]phenyl]methanol

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: [4-[[1-[2-[[4-(Hydroxymethyl)phenyl]methoxy]naphthalen-1-yl]naphthalen-2-yl]oxymethyl]phenyl]methanol
• 化学式: C₃₆H₃₀O₄
• 分子量: 526.632
• InChiKey: DOQULAURJNMCKQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.2
• 重原子数：
  40
• 可旋转键数：
  9
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  58.9
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  [4-[[1-[2-[[4-(Hydroxymethyl)phenyl]methoxy]naphthalen-1-yl]naphthalen-2-yl]oxymethyl]phenyl]methanol 在 三溴化磷 作用下， 以 二氯甲烷 为溶剂， 反应 4.0h， 以72%的产率得到(S)-(-)-2,2'-bis(p-bromomethylbenzyloxy)-1,1'-binaphthyl
  参考文献：
  名称：

  某些手性单环丁苯橡胶和双环环烷的合成，络合和光异构化研究

  摘要：

  已经合成了具有小的和大的刚性腔的各种手性丁苯橡胶。具有二苯乙烯桥连单元的双环环烷也已经合成。某些芪甲酚与TCNQ或TCNE形成电荷转移络合物。还已经研究了双环烷的光异构化。

  DOI：

  10.1016/j.tet.2007.06.015
• 作为产物：
  描述：

  对甲基苯甲酸乙酯 在 N-溴代丁二酰亚胺(NBS) 、 lithium aluminium tetrahydride 、 potassium carbonate 作用下， 以 四氢呋喃 、 四氯化碳 、 N,N-二甲基甲酰胺 为溶剂， 反应 60.0h， 生成 [4-[[1-[2-[[4-(Hydroxymethyl)phenyl]methoxy]naphthalen-1-yl]naphthalen-2-yl]oxymethyl]phenyl]methanol
  参考文献：
  名称：

  某些手性单环丁苯橡胶和双环环烷的合成，络合和光异构化研究

  摘要：

  已经合成了具有小的和大的刚性腔的各种手性丁苯橡胶。具有二苯乙烯桥连单元的双环环烷也已经合成。某些芪甲酚与TCNQ或TCNE形成电荷转移络合物。还已经研究了双环烷的光异构化。

  DOI：

  10.1016/j.tet.2007.06.015

文献信息

• Synthesis, complexation, and photoisomerization studies on some chiral monocyclic stilbenophanes and bis-cyclophanes
  作者：Perumal Rajakumar、Subramaniyan Selvam

  DOI：10.1016/j.tet.2007.06.015

  日期：2007.9

  Various chiral stilbenophanes with small and large rigid cavities have been synthesized. Bis-cyclophanes with a stilbene-bridging unit have also been synthesized. Some of the stilbenophanes form charge transfer complexes with either TCNQ or TCNE. Photoisomerization of the bis-cyclophanes has also been studied.

  已经合成了具有小的和大的刚性腔的各种手性丁苯橡胶。具有二苯乙烯桥连单元的双环环烷也已经合成。某些芪甲酚与TCNQ或TCNE形成电荷转移络合物。还已经研究了双环烷的光异构化。
• Synthesis and structural characterization of chiral dicationic imidazolophanes
  作者：Perumal Rajakumar、Subramaniyan Selvam、Manickam Dhanasekaran

  DOI：10.1016/j.tetlet.2005.06.159

  日期：2005.9

  Various chiral dicationic benzimidazolophanes were obtained from optically pure (S)-BINOL, benzimidazole and a suitable aryl alkyl dibromide. (c) 2005 Elsevier Ltd. All rights reserved.
• BINAPHTHYL COMPOUNDS AND THERMOPLASTIC RESINS
  申请人：[en]MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：WO2024117265A1

  公开（公告）日：2024-06-06

  The present invention relates to binaphthyl compounds of the formula I) that are suitable as monomers for preparing thermoplastic resins, such as polycarbonate resins, which have beneficial optical and mechanical properties and can be used for producing optical devices. where X1and X2are independently selected from -CH2OH and -C(O)ORX, where Rxis selected from the group consisting of hydrogen, phenyl, benzyl and C1-C4-alkyl; A1and A2are independently e.g. mono- or polycyclic arylene having from 6 to 26 carbon atoms as ring members or mono- or polycyclic hetarylene having a total of 5 to 26 atoms, which are ring members; R1and R2are independently selected from the group consisting of halogen, C2-C3- alkynyl, CN, R, OR, CHsR'3-s, NR2, C(O)R and CH=CHR", it being possible that R1and R2are identical or different if p+q>1, where s on each occurrence is 0, 1 or 2; p and q are independently 0, 1 or 2.
• Synthesis and antibacterial activity of some novel chiral fluorophoric biscyclic macrocycles
  作者：Perumal Rajakumar、Subramaniyan Selvam、Vellaisamy Shanmugaiah、Narayanasamy Mathivanan

  DOI：10.1016/j.bmcl.2006.12.071

  日期：2007.9

  Synthesis of chiral permanent fluorophoric biscyclic macrocycles incorporating anthraquinone and (S)-BINOL core is described. Interestingly, the biscyclic macrocycle I exhibited remarkable antibacterial activity against most of the pathogenic bacteria in the tested concentrations as compared to the other three compounds 2, 14 and 17 as well as the test control, tetracycline. Further biscyclophanes 1 and 2 exhibited permanent. fluorescence sensing property even under highly acidic conditions. (C) 2007 Elsevier Ltd. All rights reserved.