2-furaldehyde thiosemicarbazone nickel(II) | 112531-16-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 杂芳族化合物
• 英文名称: 2-furaldehyde thiosemicarbazone nickel(II)
• 英文别名: bis(2-furaldehydethiosemicarbazonato)nickel(II)
• CAS: 112531-16-5；79372-49-9
• 化学式: C₁₂H₁₂N₆NiO₂S₂
• 分子量: 395.088
• InChiKey: YSTSXGOQLANKFI-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  furan-2-aldehyde thiosemicarbazone 、 nickel(II) chloride hexahydrate 在 CH₃COONa 作用下， 以 乙醇 、 水 为溶剂， 以70%的产率得到2-furaldehyde thiosemicarbazone nickel(II)
  参考文献：
  名称：

  Transition Metal Complexes of Furan‐2‐aldehyde Thiosemicarbazone

  摘要：

  Cu(II), Ni(II), Zn(II), and Co(III) complexes of furan-2-aldehyde thiosemicarbazone (HL) have been synthesized and are characterized by elemental analyses, molar conductance measurements, magnetic susceptibility measurements, UV-Vis, IR, (1)H NMR and EPR spectra. The molar conductivities show that all of the complexes are non-electrolytes. The IR spectra suggest coordination of the thiosemicarbazone to the metal through azomethine nitrogen and thiolate sulfur atoms. The furan oxygen appears not to be coordinated in all complexes. The complexes have the formulas Cu(2)L(2)Cl(2), NiL(2), ZnL(2) and CoL(3) where L corresponds to the anionic thiosemicarbazone.

  DOI：

  10.1081/sim-120023500

文献信息

• Umapathy, P.; Budhkar, A. P.; Dorai, C. S., Journal of the Indian Chemical Society, 1986, vol. 63, p. 714 - 721
  作者：Umapathy, P.、Budhkar, A. P.、Dorai, C. S.

  DOI：——

  日期：——
• Chatterjee; Duggal; Agarwala, Journal of the Indian Chemical Society, 1989, vol. 66, # 8-10, p. 550 - 557
  作者：Chatterjee、Duggal、Agarwala、Dey

  DOI：——

  日期：——
• Aravindakshan, K. K.; Nair, C. G. R., Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 1981, vol. 20, # 7, p. 684 - 687
  作者：Aravindakshan, K. K.、Nair, C. G. R.

  DOI：——

  日期：——