[Th(4-[N-(4'-methoxybenzylidene)amino]antipyrine semicarbazone)2Br4] | 837367-06-3

• 英文名称: [Th(4-[N-(4'-methoxybenzylidene)amino]antipyrine semicarbazone)2Br4]
• 英文别名: [Th(MBAAPS)2Br4]
• CAS: 837367-06-3
• 化学式: C₄₀H₄₄Br₄N₁₂O₄Th
• 分子量: 1308.52
• InChiKey: GVKRFBWKIWIHGZ-KGKIVJEFSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  4-[N-(4'-methoxybenzylidene)amino]antipyrine semicarbazone 、 溴化钍 以 甲醇 为溶剂， 以78%的产率得到[Th(4-[N-(4'-methoxybenzylidene)amino]antipyrine semicarbazone)2Br4]
  参考文献：
  名称：

  Studies on Some Thorium(IV) Complexes with High Coordination Numbers Derived from Semicarbazones of 4‐Aminoantipyrine

  摘要：

  The interaction of thorium(IV) salts with 4 [N-(benzylidene)amino] antipyrine semicarbazone (BAAPS), 4[N-(4-methoxybenzylidene)amino] antipyrine semicarbazone (MBAAPS), 4[N-(4'-dimethoxyaminobenzylidene)amino]antipyrine semicarbazone (DABAAPS), 4[N-(2'-nitrobenzylidene)amino]antipyrine semicarbazone (2'-NO(2)BAAPS), and 4[N-(3'-nitrobenzylidene)amino]antipyrine semicarbazone (3-NO(2)BAAPS) in non-aqueous solvents resulted in the formation of [ThL2X4] (N = Cl, Br, or NCS), [ThL2I2]I-2, [ThL2](ClO4)(2) or [ThL(NO3)(4)] (L = BAAPS, MBAAPS, DABAAPS, 2-NO(2)BAAPS, or 3-NO(2)BAAPS). All of these compounds were characterized by elemental analyses, electrical conductivity, IR, and thermal methods. X-ray powder diffraction studies of a representative complex were also undertaken. Th(IV) displays the coordination numbers 6, 8, 10, and 11 in these compounds depending on the nature of the coordinated anion and the stoichiometry.

  DOI：

  10.1081/sim-200026274