2-methyl-1,1-diiodo-1-telluracyclopentane | 99218-04-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氧唑烯
• 英文名称: 2-methyl-1,1-diiodo-1-telluracyclopentane
• 英文别名: 2-Methyl-1-telluracyclopentane-1,1-diiodide；1,1-diiodo-2-methyl-1λ4-tellurolane
• CAS: 99218-04-9
• 化学式: C₅H₁₀I₂Te
• 分子量: 451.543
• InChiKey: MUPPORQAENHWDH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.48
• 重原子数：
  8
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  2-methyl-1,1-diiodo-1-telluracyclopentane 、 碘甲烷 在 sodium tetrahydroborate 作用下， 生成 1,2-dimethyl-1-iodo-1-telluracyclopentane
  参考文献：
  名称：

  Synthesis and configurations of 2-methyl-1-organo-1-halo-1-telluracyclopentanes

  摘要：

  DOI：

  10.1016/0022-328x(85)87446-5
• 作为产物：
  描述：

  1,4-二溴戊烷 在 碲化氢 、 sodium iodide 作用下， 以 various solvent(s) 为溶剂， 反应 2.0h， 生成 2-methyl-1,1-diiodo-1-telluracyclopentane
  参考文献：
  名称：

  Synthesis and configurations of 2-methyl-1-organo-1-halo-1-telluracyclopentanes

  摘要：

  DOI：

  10.1016/0022-328x(85)87446-5

文献信息

• Synthesis, spectroscopic characterization, and in vitro antimicrobial study of novel organotellurium (IV) diphenyldithiocarbamate derivatives
  作者：Chandan Maurya、Sangeeta Bajpai、Pramod Kumar Kushwaha、Umesh Chand、Sunita Singh

  DOI：10.1080/17415993.2024.2360441

  日期：2024.7.3

  Three novel organotellurium (IV) derivatives of diphenyldithiocarbamate, C4H8Te[(CS2) N(C6H5)2]2 (1), (C2H5)2Te[(CS2) N(C6H5)2]2 (2), and C4H7(CH3)Te[(CS2) N(C6H5)2]2 (3) have been synthesized by t...

  二苯基二硫代氨基甲酸酯的三种新型有机碲 (IV) 衍生物：C4H8Te[(CS2) N(C6H5)2]2 (1)、(C2H5)2Te[(CS2) N( )2]2 (2) 和 C4H7(CH3) Te[(CS2) N( )2]2 (3) 已通过...合成
• AL-RUBAIE, ALI, Z.;AL-SHIRAYDA, HATIF, A., J. ORGANOMET. CHEM., 1985, 294, N 3, 315-319
  作者：AL-RUBAIE, ALI, Z.、AL-SHIRAYDA, HATIF, A.

  DOI：——

  日期：——
• AL-RUBAIE, ALI Z.;AL-SHIRAYDA, HATIF. A.;AUOOB, ALA I., J. ORGANOMET. CHEM., 356,(1988) N 1, C. 49-55
  作者：AL-RUBAIE, ALI Z.、AL-SHIRAYDA, HATIF. A.、AUOOB, ALA I.

  DOI：——

  日期：——
• 2-Methyl-1-organo-1-halo-1-telluracyclopentane: synthesis, solution properties, and configurational studies
  作者：Ali Z. Al-Rubaie、Hatif A. Al-Shirayda、Ala I. Auoob

  DOI：10.1016/0022-328x(88)80672-7

  日期：1988.11
• Synthesis, Characterization and in vitro Antimicrobial Activity of Organotellurium Decorated 10-Membered Tetraazamacrocyclic Complexes of Cobalt(II)
  作者：Chandan Maurya、Sangeeta Bajpai、Pramod Kumar Kushwaha、Umesh Chand、Sunita Singh

  DOI：10.14233/ajchem.2024.31358

  日期：——

  Three novel organotellurium decorated 10-membered tetraazamacrocyclic complexes of Co(II) were synthesized using template condensation of 1,1-diiodo-1-telluracyclopentane, 1,1-diodo-2-methyl-1-telluracyclopentane and 1,1-diiodo-1,1-diethyltellurium(IV) with 1,2-diaminopropane and cobalt dichloride hexahydrate in dry methanol in 2:2:1 molar ratio. The characterization of the synthesized cobalt(II) complexes was carried out using elemental analysis, spectroscopic studies (IR, proton NMR & proton decoupled carbon NMR) and molar conductance measurements. The results of these studies suggested that the complexes may be formulated as [CoLCl2] where L = C4H8Te-(NHCH2CH(CH3)NH)}2, C4H7(CH3)Te(NHCH2CH(CH3)NH)}2 and (C2H5)2Te(NHCH2CH(CH3)NH)}2. The synthesized complexes were also screened for antimicrobial activity using broth microdilution and agar disc diffusion methods.