[CdI3(N-methyl-4,4'-bipyridinium)] | 1238138-80-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [CdI3(N-methyl-4,4'-bipyridinium)]
• CAS: 1238138-80-1
• 化学式: C₁₁H₁₁CdI₃N₂
• 分子量: 664.345
• InChiKey: SCGTXSIOMVCCAO-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  N-methyl-4,4'-bipyridinium chloride monohydrate 、 cadmium(II) iodide 以 水 为溶剂， 以53%的产率得到[CdI3(N-methyl-4,4'-bipyridinium)]
  参考文献：
  名称：

  Crystal structures and visible-light excited photoluminescence of N-methyl-4,4′-bipyridinium chloride and its Zn(II) and Cd(II) complexes

  摘要：

  A new approach has been used to synthesize MQ(+) ligand (MQ(+) = N-methyl-4,4'-bipyridinium) by the reaction of 4,4'-bipyridine and chloroacetic acid, and the structure of (MQ)Cl center dot H2O (1) was first determined. Three new complexes containing MQ(+), (MQ)CdI3 (2). (MQ)ZnI3 (3), and [(MQ)znCl(1.53)I(1.47)](2)(MQ) ZnCl1.68I1.32 (4). were successfully obtained via a solution or hydrothermal method by reaction of MI2 (M = Cd, Zn) with 1, and each of which exhibits an isolated structure, with each metal atom coordinated by one MQ ligand and three terminal halogen atoms. Compounds 1-4 all display photoluminescence in the visible region under visible-light excitation, and the origins of the emissions have been assigned to ILCT for 1 and the combination of ILCT and LLCT for 2-4. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2010.05.020