bis(4-bromo-2-(cyclopentyliminomethyl)phenolato)zinc(II) | 1228436-82-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis(4-bromo-2-(cyclopentyliminomethyl)phenolato)zinc(II)
• CAS: 1228436-82-5
• 化学式: C₂₄H₂₆Br₂N₂O₂Zn
• 分子量: 599.681
• InChiKey: QGZCKJUTASXQJI-MEZXDJQBSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  4-bromo-2-(cyclopentyliminomethyl)phenol 、 zinc(II) acetate dihydrate 以 乙醇 为溶剂， 以67%的产率得到bis(4-bromo-2-(cyclopentyliminomethyl)phenolato)zinc(II)
  参考文献：
  名称：

  Synthesis and crystal structures of two zinc(II) complexes derived from 4-bromo-2-(cyclopentyliminomethyl)phenol with different solvents

  摘要：

  Two new mononuclear zinc(II) complexes, [ZnL(2)] (I) and [ZnL(2)] center dot 2MeOH (II) (HL = 4-bromo-2-(cyclopentyliminomethyl)phenol), were synthesized by the reaction of the Schiff base HL with zinc acetate in ethanol and methanol solutions, respectively. Both complexes were characterized by elemental analyses and single-crystal X-ray diffraction. The crystal of I is orthorhombic: space group Pbca, a = 14.711(3), b = 13.223(3), c = 24.870(5) , V = 4837.8(18) (3), Z = 8. The crystal of II is monoclinic: space group C2/c, a = 20.581(5), b = 10.660(3), c = 15.428(4) , beta = 119.919(3)A degrees, V = 2933.7(13) (3), Z = 4. The Zn atom in each complex is four-coordinated by two imine N and two phenolic O atoms, forming a tetrahedral geometry. Complex II possesses crystallographic two-fold rotation axis symmetry.

  DOI：

  10.1134/s1070328409110074