bis(2-hydroxyacetophenoximato)nickel(II) | 14642-58-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis(2-hydroxyacetophenoximato)nickel(II)
• 英文别名: trans-bis[ethanone, 1-(2-hydroxyphenyl)-oximato]nickel(II)；nickel(II)(2-hydroxyacetophenone oximate)2
• CAS: 14642-58-1；141195-21-3；356786-12-4
• 化学式: C₁₆H₁₆N₂NiO₄
• 分子量: 359.004
• InChiKey: NTRCPTXQEKRQOI-WJTRLQBQSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  bis(2-hydroxyacetophenoximato)nickel(II) 在 pyridine 作用下， 生成 bis(2-hydroxyacetophenoneoximato)bis(pyridine)nickel(II)
  参考文献：
  名称：

  Patil, M.S.; Patel, R. P.; Shah, J. R., Journal of the Indian Chemical Society, 1980, vol. 57, p. 120 - 123

  摘要：

  DOI：
• 作为产物：
  描述：

  1-(2-羟基苯基)-1-乙酮肟 、 nickel dichloride 在 CH₃COONa 作用下， 以 水 为溶剂， 以74%的产率得到bis(2-hydroxyacetophenoximato)nickel(II)
  参考文献：
  名称：

  Crystal, molecular, and electronic structure of Trans-bis[ethanone, 1-(2-hydroxyphenyl)-oximato]Nickel(II)

  摘要：

  AbstractThe compound [Ni(apox)2], (where apox – denotes the anion of 2‐hydroxyacetophenoneoxime, C8H8NO2−), was prepared and studied by means of spectroscopic (IR, 1H NMR, UV‐Vis) measurements and theoretical calculations employing the Hückel method. The structure was determined by X‐ray diffraction studies. The unit cell is monoclinic (space group P21/c) with dimensions a = 7.845(1), b = 9.911(2), c = 19.371(2) Å, β = 94.37(1)° and contains four formula units. Hückel investigations in comparison with the electronic excitation spectrum revealed that the two bands at 2.73 and 2.62 μm−1 can be characterised as MLCT, the band at 1.62 μm−1 as d–d transition, while the band at 2.14 cm−1 has a mixed character of both MLCT and d–d transition.

  DOI：

  10.1002/zaac.19976230199

文献信息

• Thermal behaviour and kinetic analysis of the thermogravimetric data of some copper(II), nickel(II), and palladium(II) 2-hydroxyaryloximates
  作者：M. Lalia-Kantouri、M. Hartophylles

  DOI：10.1016/0040-6031(93)80170-f

  日期：1993.9

  The thermal stability and mode of decomposition of eleven 2-hydroxyaryloxime chelates with the transition metals Cu(II), Ni(II), and Pd(II) have been studied in air atmosphere using the TG/DTA technique. In the case of copper chelates, their thermal behaviour was also studied in nitrogen atmosphere by TG/DTG.A kinetic analysis of the TG data was performed using the Coats-Redfern method to determine the apparent activation energies and the pre-exponential factor of the Arrhenius equation. Mass spectrometry was also used and possible fragmentation patterns are given and discussed.
• Surendra Babu; Krishna; Hussain Reddy, Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 2008, vol. 47, # 11, p. 1661 - 1665
  作者：Surendra Babu、Krishna、Hussain Reddy、Philip

  DOI：——

  日期：——
• Chandra, Ramesh; Singh, Rana R.; Singh, Raman M., Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1992, vol. 22, p. 311 - 320
  作者：Chandra, Ramesh、Singh, Rana R.、Singh, Raman M.

  DOI：——

  日期：——