[Pd(N,N-dimethylbenzylamine)(acetonitrile)2](NO3) | 532984-34-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Pd(N,N-dimethylbenzylamine)(acetonitrile)2](NO3)
• 英文别名: [Pd(N,N-dimethylbenzylamine)(CH3CN)2](NO3)；[Pd(dmba)(CH3CN)2](NO3)
• CAS: 532984-34-2
• 化学式: C₁₃H₁₈N₃Pd*NO₃
• 分子量: 384.731
• InChiKey: ZYBKRFVGIAYUQJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [Pd(N,N-dimethylbenzylamine)(acetonitrile)2](NO3) 、 1,2-二(4-吡啶基)乙烯 以 二氯甲烷 为溶剂， 生成 [Pd2(N,N-dimethylbenzylamine)2(NO3)2(μ-trans-1,2-bis(4-pyridyl)ethylene)]
  参考文献：
  名称：

  Thermal study of cyclopalladated complexes of the type [Pd2(dmba)2X2(bpe)]

  摘要：

  新型环金属化合物的合成、表征及热分析：[Pd2(dmba)2Cl2(μ-bpe)] (1)、[Pd2(dmba)2(N3)2(μ-bpe)] (2)、[Pd2(dmba)2(NCO)2(μ-bpe)] (3)、[Pd2(dmba)2(SCN)2(μ-bpe)] (4)、[Pd2(dmba)2(NO3)2(μ-bpe)] (5) (bpe=反-1,2-双(4-吡啶基)乙烯；dmba=N,N-二甲基苄胺)。[Pd2(dmba)2X2(μ-bpe)]配合物的热稳定性顺序为1>4>3>2>5。热分解后的最终残留物通过X射线粉末衍射表征为金属钯。

  DOI：

  10.1007/s10973-005-0903-3

文献信息

• Synthesis and characterization of mono and polymeric cyclopalladated compounds: Crystal and molecular structure of [{Pd(dmba)(ONO2)}2(μ-pz)]·H2O (pz=pyrazine)
  作者：Sandra R. Ananias、Janaina G. Ferreira、Antonio E. Mauro、Adelino V.G. Netto、Stanlei I. Klein、Regina H.A. Santos

  DOI：10.1016/j.poly.2008.10.048

  日期：2009.2

  In the treatment of cyclometallated dimer [Pd(dmba)(mu-Cl)](2) (dmba = N,N-dimethylbenzylamine) with AgNO3 and acetonitrile the result was the monomeric cationic precursor [Pd(dmba)(NCMe)(2)](NO3) (NCMe=acetonitrile) (1). Compound 1 reacted with m-nitroaniline (m-NAN) and pirazine (pz), originating [Pd(dmba)(ONO2)(m-NAN)] (2) and [Pd(dmba)(ONO2)}(2)(mu-pz)] center dot H2O (3), respectively. These compounds were characterized by elemental analysis, IR and NMR spectroscopy. The IR spectra of (2-3) display typical bands of monodentade O-bonded nitrate groups, whereas the NMR data of 3 are consistent with the presence of bridging pyrazine ligands. The structure of compound 3 was determined by Xray diffraction analysis. This packing consists of a supramolecular chain formed by hydrogen bonding between the water molecule and nitrato ligands of two consecutive [Pd-2(dmba)(2)(ONO2)2(mu-pz)] units. (c) 2008 Elsevier Ltd. All rights reserved.